PREPARATION AND CHARACTERIZATION OF ADSORBENT FROM WASTE SHEA (Vitellaria paradoxa) NUT SHELL

Authors

  • M. Musah
  • J. T. Matthew
  • Y. Azeh
  • U. M. Badeggi
  • A. I. Muhammad
  • L. M. Abu
  • P. T. Okonkwo
  • K. T. Muhammad

Keywords:

Adsorbent, Agricultural wastes, Porosity, Bulk density, Wastewater

Abstract

The activated carbons (adsorbents) prepared in this study, were from Vitellaria paradoxa nut shell following the two steps of carbonization and activation processes using H3PO4 and KOH as activating agents and were labelled as HVP for H3PO4 modified adsorbent and KVP for KOH modified adsorbent. The activated carbons were characterized using standard methods of analysis. Bulk density (g/cm3) of the carbons (HVP and KVP) were 0.72±0.03 and 0.69±0.05, and attrition (%) values of 40.76±0.16 and 42.37±0.23 were obtained for HVP and KVP respectively. Results obtained also depict the presence of carboxyl O-H and C-O groups, and the N-H of amine on the surfaces of the activated carbons. The values of pH point of charge zero (pHzpc) obtained for HVP and KVP were 6.40 and 6.60 and were less than the pH values of 6.78±0.00 and 7.18±0.01 for HVP and KVP respectively. SEM results revealed surfaces with pores with different dimensions in both HVP and KVP. Results of the study suggest that the prepared adsorbents can be effectively applied in wastewater treatment.

Dimensions

Ahmad, M. A., Puad, N. A. A. & Bello, O. S. (2014). Kinetic, equilibrium and thermodynamic studies of synthetic dye removal using pomegranate peel activated carbon prepared by microwave-induced KOH activation. Water Resources and Industry, 6:18-35

Ahmad, S. Ali, A. & Ashfaq, A. (2016). Removal of Cr (VI) from aqueous metal solution using roasted China clay. International Journal of Current Microbiology and Applied Sciences, 5(5):171-185.

Auta, M. & Hameed, B. H. (2011). Preparation of waste tea activated carbon using potassium acetate as an activating agent for adsorption of acid blue 25 dye. Chemical Engineering Journal, 171,502-509.

Bernard, E., Jimoh, A. & Odigure, J.O. (2013). Heavy metal removal from industrial wastewater by activated carbon prepared from coconut shell. Research Journal of Chemical Science, 3(8),3-9

Cardenas- Pena, A.M., Ibanez, J.G. & Vasquez-Madrano, R. (2012). Determination of the point of zero charge for electrocoagulation precipitates from an iron anode. International Journal of Electrochemical Science, 7:6142-6153.

Dawodu, F.A. & Akpomie, .K. G. (2014). Simultaneous adsorption of Ni (II) and Mn (II) ions from aqueous solution onto a Nigeria kaolinite clay. Journal of Materials Research and Technology, 3(2),129-141

Hebert, V. (2011). Bulk density of powders made easy. Retrieved on 18th June, 2015 from http:/www.brookfieldengineering.com

Hussain, O. A., Hathout, A. S., Abdel-Mobdy, Y. E., Rashed, M. M., Rahim, E. A. A. & Fonzy, A. S. M. (2023). Preparation and characterization of activated carbon from agricultural wastes and their ability to remove chlorpyrifos from water. Toxicology Reports, 10,164-154

Ioannidou, O. & Zabaniotou, A. (2006). Agricultural precursors for activated carbon production. Renewable and Sustainable Energy Review. 11(1):196-205.

Karthikeyan, G. & Ilango, S.S (2008). Adsorption of Cr(VI) on Activated Carbons Prepared from Indigenous Materials. E-Journal of Chemistry. 5(4):666-678.

Kale, A. (2019). Study on carattrition of carbon particles during regeneration of activated carbon. https://www.researchgate.net/publication/336742273

Kongsuwan, A., Patnukao, P. & Pavasant, P. (2006). Removal of metal ion from synthetic waste water by activated carbon from Eucalyptus camaldulensis Dehn Barch. The 2nd Joint International Conference on Sustainable Energy and Environment. Bangkok, Thailand. Pp1-9

Madojemu, G. O.,Eze, C. B. and Okieimen, F. E. (2020). Optimization of surface area of activated carbons prepared from coconut shells by response surface methodology. Journal of Chemical Society of Nigeria, 45(2),354-364.

Mathew, J. T., Musah, M., Azeh, Y. & Mohammed, M. (2023a). Kinetic study of heavy metal removal from pharmaceutical wastewater using geopolymer/Fe3O4 nanocomposite. Bima Journal of Science and Technology, 7(4), 154-62.

Mathew, J. T., Musah, M., Azeh, Y. & Mohammed, M. (2023b). Adsorptive Removal of Selected Toxic Metals from Pharmaceutical Wastewater using Fe3O4/ZnO Nanocomposite. Dutse Journal of Pure and Applied Sciences, 9(4a), 236-248.

Musah, M., Yerima, H., Haruna, B. & Umar, M. T. (2018). Study of the intraparticle diffusion of Cr (VI), Mn (II) and Cd (II) on modified goal coast bombax. Journal of Science and Engineering Research, 5(2),400-408.

Musah, M., Yisa, J., Suleiman, M. A. T. & Mann, A. (2016). Preparation and characterization of mesoporous functionalized activated carbon from Bombax buonopozense Calyx. American Journal of Innovative Research and Applied Sciences, 2(2),90-97

Musah, M., Birnin-Yauri,U. A. & Itodo, A. U. (2011). Removal of Pb2+ and Cr3+ ions from aqueous solution using derived Palm Kernel Shell adsorbent. Bilogical and Environmental Sciences Journal for the Tropics, 8(3),19-132.

Mussato, S.I., Fernandes, M., Rocha, G.J.M., Orfao, J.J.M., Teixeira, J.A. & Roberto, I.C. (2010). Production, characterization and application of activated carbon from brewer’s spent grain lignin. Bioresource Technology, 101,2450-2457.

Njewa, J. B., Vunain, E. & Biswic, T. (2022). Synthesis and characterization of activated carbons pepared from agro-wastes by chemical activation. Hindawi Journal of Chemistry, 1-13

Nurul, I. M., Khatton, A., Sarker, J., Sikder, H. A. & Chowdhury, A. M. (2022). Preparation and characterization of activated carbon from jute stick by chemical activation: Comparison of different activating agents. Saudi Journal of Engineering and Technology, 7(2), 12-117.

Okeimen, F. E., Ojokoh, F. I., Okeimen, C. O. & Wunana, R.A. (2004). Preparation and evaluation of activated carbon from rise husk and rubber seed shell. Chemclass, 191-196.

Rahman, M. M., Adil, M., Yusof, A. M., Kamaruzzaman, Y. B. & Ansary, R. H. (2014). Removal of heavy metals ions with acid activated carbons derived from oil palm and coconut shells. Materials, 7:3634-3650.

Rao, R. M., Bansode, R. R., Losso, J. N., Marshall, W. E. & Portier, R. J (2003). Adsorption of volatile organic compounds by pecan shell and almond shell-based granular activated carbons. Bioresources Technology, 90: 175-184.

Shaba, E. Y., Mathew, J. T., Musah, M., Mohammed, M., Muhammad, A. I. & Obetta, H. C. (2021). Adsorption of heavy metals from electroplating wastewater using guinea corn husk activated carbon. Lapai Journal of Science and Technology, 7(1),122-132.

Senthilkumaar, S., Krishna, S.K., Kalaamani, P.,Subburamaan, C.V., Ganapathy, N.S. and Kang, T.W. (2010). Kinetic approach for adsorption of organophosphorus pesticides from aqueous solution using waste jute fiber carbon. E-Journal of Chemistry. 7:511-519.

Sivikumar, K., Kannan, C. & Karthikeyan, S. (2012). Preparation and characterization of activated carbon prepared from Balsamodendron caudatun wood waste through various activation processes. Rasayan Journal of Chemistry, 5(3),321-327.

Sugumaran, P., Priya, S.V., Ravichandran, P. & Seshadri, S. (2012). Production and Characterization of Activated Carbon from Banana Empty Fruit Bunch and Delonix regia Fruit Pod. Journal of Sustainable Energy and Environment, 3,125-132

Sumithra, C., Murugavel, S.C. & Karthikeyan, S. (2014). Evaluation of dynamics and equilibrium models for the sorption of basic violet 3 on activated carbon prepared from Moringa oleifera fruit shell wastes. Carbon-Science and Technology, 6(1),342-348

Ziezio, M., Charmas, B., Jedynak, K., Hawryluk, M. & Kucio, K. (2020). Preparation and characterization of activated carbons obtained from wastes materials impregnated with phosphorus acid (V). Applied Nanoscience, 10, 4703-4716

Published

30-04-2024

How to Cite

PREPARATION AND CHARACTERIZATION OF ADSORBENT FROM WASTE SHEA (Vitellaria paradoxa) NUT SHELL. (2024). FUDMA JOURNAL OF SCIENCES, 8(2), 338-344. https://doi.org/10.33003/fjs-2024-0802-2370

Issue

Vol. 8 No. 2 (2024): FUDMA Journal of Sciences - Vol. 8 No. 2

Section

Research Articles
Copyright & Licensing

FUDMA Journal of Sciences

How to Cite

PREPARATION AND CHARACTERIZATION OF ADSORBENT FROM WASTE SHEA (Vitellaria paradoxa) NUT SHELL. (2024). FUDMA JOURNAL OF SCIENCES, 8(2), 338-344. https://doi.org/10.33003/fjs-2024-0802-2370

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