PRODUCTION AND PERFORMANCE ASSESSMENT OF MARULA (Sclerocarya birrea) BIODIESEL IN A COMPRESSION IGNITION ENGINE

Authors

  • Muyideen Abdulkadir Department of Mechanical Engineering, Waziri Umaru Federal Polytechnic
  • Adeyemi J.Ademola Federal Polytechnic, Birnin Kebbi
  • Isah Aliyu
  • Olusegun I. Lasisi Federal Polytechnic, Birnin Kebbi
  • Karim Mutalib Federal Polytechnic, Birnin Kebbi
  • A. Kamilu Sanusi Federal Polytechnic, Brinin Kebbi

DOI:

https://doi.org/10.33003/fjs-2026-1003-4599

Keywords:

Marula biodiesel, compression ignition engine, biodiesel-diesel blends, brake thermal efficiency, engine performance analysis, exhaust emission characteristics

Abstract

Interest in investigating less polluting, renewable, and non- petroleum fuels has increased due to rising fuel prices, environmental concerns, and the depletion of fossil oil reserves. It has been established that biodiesel serves as an effective substitute for conventional neat fuel in compression ignition (CI) engines. In this study, marula biodiesel was produced via a transesterification process employing methanol at a ratio of 6:1, with potassium hydroxide as the catalyst at a concentration of 1.4 wt%. The mixture was heated in a beaker placed on a hot plate with a magnetic stirrer for 30 minutes at a temperature of 60 °C and operated at a speed of 305.5 rpm. The most common physicochemical properties of marula biodiesel were determined in accordance with (ASTM D 6751 and EN 14214) Standards. The oil yield from the marula was determined to be 58.7%. The saponification value, iodine value, free fatty acid content, acid value, peroxide value, cetane number, density, viscosity, calorific value, flash point, and pour point for both marula oil and marula biodiesel were found to be 187.72 mg KOH/g, 61. 77 g /100 g, (1.72% and 0. 21%), (3.42 mg KOH/g and 0.44 mg KOH/g), (10.67 meq/kg and 2 meq/kg), (51 and 55.1), (943 and 850, (41 /sec and 5. 0 /sec),  (38.40 MJ/kg and 42. 89 MJ/kg), (240 °C and 175 °C), (5 °C and 3 °C), respectively. The generation and performance evaluation of marula biodiesel in a compression ignition engine under various load conditions are discussed in this experiment. 

Author Biography

  • Isah Aliyu

    Department of Metallurgical Engineering, Waziri Umaru Federal Polytechnic, Birnin Kebbi, 1034, Nigeria

    Principal Lecturer

References

Abed, K., Gad, M., El Morsi, A., Sayed, M., and Elyazeed, S. A. (2019). Effect of biodiesel fuels on diesel engine emissions. Egyptian journal of petroleum, 28(2), 183-188.

Alahmer, A., Rezk, H., Aladayleh, W., Mostafa, A. O., Abu-Zaid, M., Alahmer, H., . . . Ghoniem, R. M. (2022). Modeling and optimization of a compression ignition engine fueled with biodiesel blends for performance improvement. Mathematics, 10(3), 420.

https://doi.org/10.3390/math10030420

Aliyu, I., Shaibu, L., & Rufai, D. (2025). Physiochemical, Thermal, and Morphological Characteristics of Millet Husk (Pennisetum Glaucum L) for Polymer Composite Application. FUDMA Journal of Sciences (FJS), 9(12), 247–255. https://doi.org/https://doi.org/10.33003/fjs-2025-0912-4182

Aransiola, E. F., Ojumu, T. V., Oyekola, O., & Ikhu-Omoregbe, D. (2012). A study of biodiesel production from non-edible oil seeds: A comparative study.

ASTM (2023). American Society of Testing and Materials. Standard Specification for Biodiesel Fuel (B100) Blend, Philadelphia.

Attia, A. M., Nour, M., El-Seesy, A. I., & Nada, S. A. (2020). The effect of castor oil methyl ester blending ratio on the environmental and the combustion characteristics of diesel engine under standard testing conditions. Sustainable Energy Technologies and Assessments, 42, 100843.

Azuaga, I., Igbum, G., & Kyenge, B. (2018). Extraction and characterization of three tropical seedoils: Telfairia occidentalis, Hura crepitans and Cucumeropsis mannii. Chem Res J, 3, 1-8.

Bhardwaj, V., Singla, V., Gaikwad, P., & Sharma, G. (2014). Study of performance characteristics of compression ignition engine fuelled with blends of biodiesel from used cottonseed oil. International Review of Applied Engineering Research, 4(1), 1-6. ISSN, 2248-9967.

Bouaid, A., Iliuta, G., & Marchetti, J. M. (2024). Cold flow properties of biodiesel from waste cooking oil and a new improvement method. Heliyon, 10(17), e36634.

Chomini, M., Daspan, A., Kambai, C., Chomini, A., Bassey, E., Fatoke, V., & Rabiu, A. (2020). Assessment of Biodiesel Fuel Potentials of Seed Crude Oil Extracts of Balanites aegyptiaaca (L.) Del. Journal of Applied Sciences and Environmental Management, 24(8), 1467-1473.

Costa do Nascimento, D. b., Souza, M. c. P. d. O., Hentges, L. d. O., Dias, R. M., Marinho Barbosa Neto, A., & Costa, M. C. a. o. d. (2024). Mixture Flash Point Calculation: Recent Advances and a Closer Look at Biodiesel. ACS Chemical Health & Safety, 31(1), 22-43.

Dagde, K. (2019). Extraction of vegetable oil from avocado seeds for production of biodiesel. Journal of Applied Sciences and Environmental Management, 23(2), 215-221.

Dhamodaran, G., Krishnan, R., Pochareddy, Y. K., Pyarelal, H. M., Sivasubramanian, H., and Ganeshram, A. K. (2017). A comparative study of combustion, emission, and performance characteristics of rice-bran-, neem-, and cottonseed-oil biodiesels with varying degree of unsaturation. Fuel, 187, 296-305.

Duc, K. N., Duy, V. N., Hoang-Dinh, L., Viet, T. N., & Le-Anh, T. (2019). Performance and emission characteristics of a port fuel injected, spark ignition engine fueled by compressed natural gas. Sustainable Energy Technologies and Assessments, 31, 383-389.

Ejilah, R., Kamal, D., & Gambo, B. (2017). Influence of Marula Oil Methyl Ester–Diesel Fuel Mixtures on the Performance of a Variable Load Compression Ignition Engine. European Journal of Advances in Engineering and Technology, 4(6), 457-465.

Enweremadu, C., & Rutto, H. (2016). Performance characteristics of green diesel from marula (Sclerocarya birrea) oil in diesel engine. Journal of Biobased Materials and Bioenergy, 10(3), 159-167.

European Committee for Standardization. (2020). EN 14214: Automotive fuels-fatty acid methyl esters (FAME) for diesel engines-requirements and test methods.

Fapetu, O. P., Akinola, A. O., Lajide L. L., and Osasona, A. B. (2018) “Physicochemical Characteristics Study of Oil Extracted From Raffia Palm Seed” Journal of Engineering and Engineering Technology (FUTAJEET) 12 (1): 102-114

Gangil, S., Singh, R., Bhavate, P., Bhagat, D., & Modhera, B. (2016). Evaluation of engine performance and emission with methyl ester of Karanja oil. Perspectives in Science, 8, 241-243.

Gaurav, D., & Sharma, M. (2013). Performance evaluation of diesel engine using biodiesel from pongamia oil. International Jounal of Renewable energy research, 2(3), 435-440.

Gautam, R., Chauhan, B. S., & Lim, H. C. (2022). Influence of variation of injection angle on the combustion, performance and emissions characteristics of jatropha ethyl ester. Energy, 254, 124436.

Gunstone, F. D. (2004). Rapeseed and canola oil: production, processing, properties and uses: CRC Press.

Ingle, S., & Nandedkar, V. (2013). Castor oil Biodiesel an alternative fuel for Diesel in compression ignition engine. Journal of Mechanical and Civil Engineering (IOSR-JMCE) p, 10-13.

Ismail, S., Abu, S., Rezaur, R., and Sinin, H. (2014). Biodiesel production from castor oil and its application in diesel engine. ASEAN Journal on Science and Technology for Development, 31(2), 90-100

Kalbande, S., Pawar, S., & Jadhav, S. (2007). Production of Karanja biodiesel and its utilization in diesel engine generator set for power generation. Karnataka Journal of Agricultural Sciences, 20(3), 680-683.

Karthikeyan, S., & Prathima, A. (2016). Emission analysis of the effect of carbon nanowires in biodiesel–ethanol blends. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 38(21), 3195-3201.

Krahl, J., Munack, A., Schröder, O., Stein, H., and Bünger, J. (2003). Influence of biodiesel and different designed diesel fuels on the exhaust gas emissions and health effects. SAE transactions, 2447-2455.

Luque-Rodriguez, J.M. (2005). Extraction of fatty acids from grape seed by superheated hexane, Talanta 68, 126-130.

Maawa, W., Mamat, R., Najafi, G., Ali, O. M., & Aziz, A. (2015). Engine performance and emission of compression ignition engine fuelled with emulsified biodiesel-water. Paper presented at the IOP Conference Series: Materials Science and Engineering.

Manirafasha, E., Jiao, K., Zeng, X., Xu, Y., Tang, X., Sun, Y., . . . Jing, K. (2020). Processing of Microalgae to Biofuels Microalgae Cultivation for Biofuels Production (pp. 111-128): Elsevier.

Martín, C., Moure, A., Martín, G., Carrillo, E., Domínguez, H., and Parajo, J. C. (2010). Fractional characterisation of jatropha, neem, moringa, trisperma, castor and candlenut seeds as potential feedstocks for biodiesel production in Cuba. Biomass and bioenergy, 34(4), 533-538.

Mujtaba, M., Kalam, M., Masjuki, H., Gul, M., Soudagar, M. E. M., Ong, H. C., . . . Yusoff, M. (2020). Comparative study of nanoparticles and alcoholic fuel additives-biodiesel-diesel blend for performance and emission improvements. Fuel, 279, 118434.

Mustapha, A. O., Afolabi, Y. T., & Osunniran, W. A. (2025). Synthesis, Characterization and Optimization of Alumina-Supported, Biogenic CaO Catalysts for Enhanced Biodiesel Production from Waste Peanut Oil. Records of Chemical Sciences, 4(3), 1-15.

Nalla, B. T., Subbiah, G., Acharya, S. K., Sunil Kumar, M., Patel, C., Kumar Sahu, K., . . . Kamakshi Priya, K. (2025). Ignition and emission analysis of a hydrogen-assisted diesel engine fueled with waste Sapota seed biodiesel. Clean Energy, 9(6), 279-292.

Ndaya, D. M. (2013). Biodiesel Production From Candlenut And Calodendrum Capense Seeds: Process Design And Technological Assessment. University of Nairobi.

Nguyen, T. V., Nguyen, K. D., Ho, N. X., & Nguyen, V. D. (2020). Engine performance and combustion characteristics of a direct injection compression ignition engine fueled waste cooking oil synthetic diesel. International Journal of Coal Science & Technology, 7, 560-570.

Padmanabhan S, Rajasekar S, Ganesan S, Saravanan S and Chandrasekaran M (2017). performance and emission analysis on CI engine using Soapnut oil as biofuel ARPN Journal of Engineering and Applied Sciences 12(8) pp 2491-95

POWO. (2021). Plants of the World Online. Facilitated by the Royal Botanic Gardens, Kew. Published on the Internet.

Prasad, B. N., Pandey, J. K., & Kumar, G. (2020). Impact of changing compression ratio on engine characteristics of an si engine fueled with equi-volume blend of methanol and gasoline. Energy, 191, 116605.

Sahoo, P., Das, L., Babu, M., and Naik, S. (2007). Biodiesel development from high acid value polanga seed oil and performance evaluation in a CI engine. Fuel, 86(3), 448-454.

Sakthivel, P., Subramanian, K., & Mathai, R. (2020). Effects of different compression ratios and spark timings on performance and emissions of a two-wheeler with 30% ethanol-gasoline blend (e30). Fuel, 277, 118113.

Sathish, T., & Singaravelu, D. K. (2020). Diesel Engine Performance on Chlorella vulgaris Biodiesel.

Selvakumar, R., Nithiyananadam, T., & Senthilkumar, P. (2015). Theoretical Model to Predict the Ignition Delay and its Effects on Performance and Emission Characteristics of Biodiesel Fueled Diesel Engine. Journal of Chemical and Pharmaceutical Sciences, JCHPS Special(6), 19-23.

Senthil, R., & Vijay, G. A. (2023). Review of physicochemical properties and spray characteristics of biodiesel. Environmental Science and Pollution Research, 30(25), 66494-66513.

Senthilkumar, R., Ramadoss, K., & Prabu, M. (2012). An effective experimental investigation on 4-stroke single cylinder CI engine using cotton seed biofuels. Paper presented at the IEEE-International Conference On Advances In Engineering, Science And Management (ICAESM-2012).

Singh, J., & Gu, S. (2010). Commercialization potential of microalgae for biofuels production. Renewable and sustainable energy reviews, 14(9), 2596-2610.

Suardi, S., Mahmuddin, F., Klara, S., Tasrief, M., Pawara, M. U., Hijriah, H., & Jaya, M. R. F. (2024). Performance and emission characteristics of diesel engines using biodiesel from waste cooking oil with cetane number improver. International Journal of Marine Engineering Innovation and Research, 9(3), 528-536.

Suleiman, I. A., Abubakar, S., Kaisan, M. U., Magaji, S., Abubakar, A. S., Shitu, S., . . . Umaru, S. (2020). Production and performance appraisal of biodiesel derived from used cooking oil on compression ignition engine. FUDMA Journal of Sciences, 4(2), 658-672.

Tesfa, B., Mishra, R., Gu, F., & Ball, A. (2011). Combustion characteristics of CI engine running with biodiesel blends. Paper presented at the International Conference on Renewable Energies and Power Quality (ICREPQ'11).

Thokchom, S. S. (2024). Numerically comparative assessment of different biodiesel & its blends on performance, combustion and emission characteristics. Industrial Crops and Products, 209, 117900.

Verma, B., Bundel, B. R., & Sharma, A. (2019). Study of Performance and Emission Characteristics of Non-Edible Biodiesel as a Sustainable Fuel in Diesel Engine. Paper presented at the IOP Conference Series: Materials Science and Engineering.

Yunus, M., & Zuru, A. (2017). Kinetics study of balanites aegyptiaca oil transesterification for the production of biodiesel. Nigerian Journal of Chemical Research, 22(1), 9-19.

(a) Collected Ripe Marula Fruits, (b) Marula Fruit Exposed, (c) Dry Exposed Marula Fruit, and (d) Marula Fruit kernel

Downloads

Published

04-02-2026

How to Cite

Abdulkadir, M., J.Ademola, A., Aliyu, I., Lasisi, O. I., Mutalib, K., & Sanusi, A. K. (2026). PRODUCTION AND PERFORMANCE ASSESSMENT OF MARULA (Sclerocarya birrea) BIODIESEL IN A COMPRESSION IGNITION ENGINE. FUDMA JOURNAL OF SCIENCES, 10(3), 109-118. https://doi.org/10.33003/fjs-2026-1003-4599

Most read articles by the same author(s)