DEVELOPMENT OF BIODEGRADABLE LUBRICATING OIL FOR TURBINE BEARING FROM PALM KERNEL AND CASTOR OILS
Abstract
The search for sustainable and environmentally friendly alternatives to conventional mineral-based oil lubricants has led to increasing research into bio-based lubricants for industrial applications. This study develops biodegradable lubricating oil for turbine bearing from palm kernel and castor oils through chemical modification and additive blending. Using transesterification method, the oils were converted to their various methyl esters and blended with additives such as ethylene glycol, ascorbic acid, trimethylopropane, and graphene. Physiochemical evaluations of both palm kernel and castor developed lubricating oils showed improved viscosity, pour point, thermal stability, neutralization number, and flash point against their natural oils. While their tribological evaluation revealed that among the developed samples, Palm kernel oil-based turbine lubricant 1 (PKOTL1) exhibited the best tribological properties having the lowest friction coefficient (0.047), with less frictional force (2.617N), as against the mineral oil ISO VG6 conventionally used for lubricating turbine bearings with coefficient of friction (0.051) and frictional force (2.862N), this improved tribological properties were as a result of the additives blend in the development of the bio lubricating oil. Among the developed castor oil turbine lubricant, sample (COTL3) have the lowest coefficient of friction (0.058), less frictional force (3.242N) and low wear scar diameter (0.49mm). The study confirms that the modified vegetable oils are suitable, eco-friendly alternatives to mineral-based turbine lubricants with competitive performance with that of mineral oil ISO VG46.
References
Alamu, O. J., Akintola, T. A., Enweremadu, C. C., & Adeleke, A. E. (2008). Characterization of palm-kernel oil biodiesel produced through NaOH-catalysed transesterification process. Scientific Research and Essay, 3(7), 308-311. https://doi.org/10.5897/SRE.9000262
Alhassan, M., Almustapha, M. N., Mohammed, M. L., Lawal, A. M., Adamu, M., & Shamsideen, U. (2024). Production of biolubricant blend from jatropha curcas oil. Fudma journal of sciences, 7(6), 14 - 22. https://doi.org/10.33003/fjs-2023-0706-2168
Aminu, O. I., Ademoh, N. A., Lawal, S. A., Adedipe, O., Aliyu, O. A. (2024). Characterization of Palm kernel oil and Castor Oil as Potential Bio Lubricants for Power Plant Turbine Bearings. [Paper presentation] National Engineering Conference, Nigerian Institution of Mechanical Enginers, Minna Chapter.
Bamgboye, A. I., & Hansen, A. C. (2008). Prediction of Cetane Number of Biodiesel Fuel from the Fatty Acid Methyl Ester (FAME) Composition. International Agrophysics, 22(1), 21-29.
Brajendra, K. S., Atanu, A., Zengshe, L., & Sevim, Z. E. (2006). Chemical modification of vegetable oils for lubricant applications. Journal of the American Oil Chemistry Society, 83(2), 129-136. https://doi.org/10.1007/s11746-006-1185-z
Bilal, S., Mohammed-Dabo, I. A., Nuhu, M., Kasim, S. A., Almustapha, I. H., & Yamusa, Y. A. (2013). Production of bio lubricant from jatropha curcas seed oil. Journal for Chemical Engineering and Material Science, 4(6), 72-79. https://doi.org/10.5897/JCEMS2013.0164
Biniyam T. A., Lidya D., Desta T., Hanan E. & Gebremedhn T. (2015). Production of Biolubricant from Castor (Ricinus) Oil. International Journal of Engineering Innovation & Research, 4 (5), 2277 5668. https://doi.org/10.1016/J.MATPR.2021.04.042
Claudius, A. A. (2014). Nigeria electricity industry: Issues, challenges and solutions. Canaan Land, Ogun State: Covenant University Press.
Demirbas, A., Al-Sasi, B. O., & Nizami, A. S. (2017). Recent Volatility in the Price of Crude Oil. Energy Sources, Part B: Economics, Planning, and Policy, 12, 408-414. https://doi.org/10.1080/15567249.2016.1153751
Egbuna, S. O., Nwachukwu, U. J., Agu, C. M., Asadu, C. O., & Okolo, B. (2021). Production of biolubricant samples from palm kernel oil using different chemical modification approaches. Engineering Reports, 3(11), 12-42. https://doi.org/10.1002/eng2.12422
Ejeromedoghene, O. (2021). Acid-catalyzed transesterification of palm kernel oil (PKO) to biodiesel. Materials Today: Proceedings, 47, 1580-1583. https://doi.org/10.1016/J.MATPR.2021.04.042
Emodi, N. V., & Yusuf, S. D. (2015). Improving Electricity Access in Nigeria: Obstacles and the Way Forward. International Journal of Energy Economics and Policy, 5(1), 335351. https://www.econjournals.com/index.php/ijeep/article/view/1041
Jain, S., & Sharma, M. P.(2010). Kinetics of Acid Base Catalyzed Transesterification of Jatropha curcas Oil. Bioresource Technology, 101(20) 7701-7706. https://doi.org/10.1016/j.biortech.2010.05.034.
Kamhoua, A., Mengata, M. G., Monkam, L., Moukengue, I. A. (2023). Determination at Variable Temperatures and Analysis of the Physico-Thermal Properties of Palm Kernel and Castor Oil Methyl Esters as Dielectrics for Power Transformers. International Journal of Heat and Technology, 41(1), 63-71. https://doi.org/10.18280/ijht.410107.
Keera, S. T., El Sabagh, S. M., Taman, A. R. (2018). Castor oil biodiesel production and optimization. Egyptian Journal of Petroleum. Retrieved from http://creativecommons.org/licenses/by-nc-nd/4.0/.
Lawal, S. A., Choudhury, I. A., & Nukman, Y. (2011). Application of vegetable oil-based metalworking fluids in machining ferrous metalsA review. International Journal of Machine Tools and Manufacture, 52(1), 1-12. https://doi.org/10.12691/ajmse-3-2-3
Owuna, F. J., Dabai, M. U., Sokoto, M. A., Dangogo, S. M., Bagudo, B. U., Birnin-Yauri, U. A., Hassan, L. G., Sada, I., Abubakar, A. L., & Jibrin, M. S. (2019). Chemical modification of vegetable oils for the production of biolubricants using trimethylolpropane: A review. Egyptian Journal of Petroleum. https://doi.org/10.1016/j.ejpe.2019.11.004
Pathmasiri, T. K. K. S., Perera, G. I. P., & Gallage, R. (2019). Investigation of palm-castor oil blends as base stocks of bio-lubricants for industrial applications. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. https://doi.org/10.1080/15567036.2019.1643425
Siemens Operation and Maintenance manual. (2011). Siemens gas turbine for Geregu, Nigeria. Siemens Germany Inc.
Woma, T. Y. (2021). Tribological evaluation of lubricant developed from some selected vegetable based oils for industrial applications. [Unpublished doctoral dissertation], Federal University of Technology Minna, Nigeria.
Woma, T. Y., Lawal, S. A., Abdulrahman, A. S., & Moses, O. (2019). Nigeria Palm kernel oil as suitable basestock for biolubricant production. Journal of Tribology, 23, 97-112.
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