REMOVAL OF LEAD (Pb2+) IONS FROM AQUEOUS SOLUTION BY ADSORPTION USING SUGARCANE BAGASSE ACTIVATED CARBON COATED WITH MAGNETIC NANOPARTICLES
Abstract
An experiment to remove lead (II) ions through adsorption from its aqueous solution using Sugarcane Bagasse Activated carbon (SBAC) was carried out. As one of the ways employ to reduce the high cost of treatment of industrial effluents. Agricultural wastes could be considered as suitable material for the production of Activated Carbon due it high carbon contents, environmentally friendly and low cost of production. In this work, activated carbon was produced by chemical activation with sulphuric acid (H2SO4) of sugarcane bagasse materials. It was then coated with magnetic nanoparticle (Fe3O4) prepared by chemical precipitation of Fe2+ and Fe3+ salt from aqueous solution and tested for its efficiency as an adsorbent for the removal of Lead(II) ion from aqueous solution .The surface morphology, structural and functional groups present were investigated using scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy. Shift and disappearance of some adsorption bands in the sugarcane bagasse activated carbon coated with magnetic nanoparticles testify the formation of the composite. Optical properties were determined using UV Vis spectroscopy shows a wavelength ( of 400nm. Adsorption parameters such as effect of pH, contact time, initial concentration of Lead ion and adsorbent dosage were studied. Neutral medium was the optimum pH condition needed for the removal of lead with the percentage removal efficiency of 91%. It was found to be highly efficient at 0.4g of the dosage and at contact time of 60 minutes. This sugarcane bagasse is useful in adsorbing heavy metal in an aqueous solution
References
Abbas Qassar (2019). Understanding the UV-Vis Spectroscopy for Nanoparticles. Journal of Nanomaterials and Molecular Nanotechnology, 8(3) 1-3.
Ab Latif Wani, Anjum Ara and Jawed Ahmad Usmani (2015).Lead toxicity: a review.Interdisciplinary Toxicology,8(2):55-64.
Abdullah Chandrah Sekhar Talari, Marcela A. Garcia Martinez,Zanyar Movasaghi, Shazza Rehman and Ihtesham Ur Rehman (2017).Advances in Fourier Transform Infrared (FTIR) Spectroscopy of Biological Tissues. Applied Spectroscopy Reviews, 52(5) 456-506.
Aguadoj, Arsuaga J.M, Arencibia A., Lindo M. and Gaseon V.(2009). Aqueous heavy metals removal by adsorption on amino-functionalized mesoporous silica . Journal of Hazardous Materials, (163) 213-221.
Ahmad A. A., Hameed B. H. and Aziz N.(2006). Adsorption of direct on palm ash: kinetic and equilibrium modeling. Journal of Hazardous Materials,14(1):70-76.
Alexander (1999). Bioaccumulation, bioconcentration, biomagnifications.Environmental Geology.Encylopedia of Earth Science.pp.43-44.
Chilton Ng,Bansode Rishipal, Marshall Wayne,Losso Jacques and Rao Ramu (2002).Process description and production of cost to manufacture sugarcane bagasse based granular activated carbon.International Sugar Journal, 104(1245):401-408.
C.H.Tan, Y.C.Moo, M. Z. Matjafri and H. S. Lim (2014).UV Spectroscopy Determination of Aqueous Lead and Copper Ions in water. In the Proceedings of the 2014 SPIE –International Society for Optical Engineering Conference.
Dada A. O., Ojediran, J.O. and Olalekan A. P.(2013). Sorption of Pb2+ from Aqueous Solution unto Modified Rice Husk: Isotherms Studies. Advances in Physical Chemistry,1-6.
Goyal, Roop Chand Bansal and Meenakshi (2005). Activated Carbon Adsorption. Taylor and Francis Group.
H. Kaur (2013).Spectroscopy. A Publication of Pragati Prakashan.
Kaghazchi, Mansooreh Soleimani, and Tahereh (2007). Agricultural waste conversion to activated carbon by Chemical Activation with Phosphoric Acid. Chemical Engineering and Technology, 30(5):649-654.
M. A. Tadda, A Ahsan, A.Shitu, M. Elsergany, T. Arunkumar, Bipin Jose, M Abdur Razzaque and N. N. Nik Dawud (2016).Review on activated carbon: process, application and prospects. Journal of Advanced Civil Engineering Practice and Research, 2(1):7-13.
Mohsen A.Hashem (2007).Adsorption of lead ions from aqueous solution by okra wastes.International Journal of Physical Sciences,2(7):178-184.
Muhammad A. S., Uduma U. A. and Sani S. (2018). Kinetics and isotherms of lead (II) ions adsorption onto chelating schiff base derived from 2-hydroxy-2-phenylacetophenone and 2-aminobenzoic acid.FUDMA Journal of Sciences (FJS), 2(1):206-213.
P. Panneersalvam, Norhashimah Morad and Kah Air Tan (2010). Magnetic nanoparticles(Fe3O4) impregnated onto tea waste for the removal of nickel(II) from aqueous solution. Journal of Hazardous Materials,186(2011):160-168.
Pradhan and Subhashree (2011).Production and characterization of activated carbon produced from a suitable industrial sludge,Material Science,National Institute of Technology, Rourkela,India.
R. Wannahari, P. Sannasi, M. F.M. Nordin and H. Mukhtar (2006).Sugarcane bagasse derived nano magnetic adsorbent composite (SCB-NMAC) for removal of Cu2+ from aqueous solution. ARPN Journal of Engineering and Applied Sciences, 13(1):1-9.
Saleh, Martin Koller and Hosam M.(2018). Introductory Chapter: Introducing Heavy Metals. Heavy Metals, Saleh and Hosam El-Din IntechOpen Limited,pp1-3314.
Tran Van Thuan, Pham Van Thinh, Bui Thi Phuong Quynh, Huynh Thanh Cong Vo Ngoc Thuan and Long Giang Bach (2016). Production of activated carbon from sugarcane bagasse by chemical activation with ZnCl2: prepared and characterization study. Research Journal of Chemical Sciences,6(5):42-47.
Zak KA, Abrishami ME, Majid WHA and Yousefi R (2010). Effects of Annealing Temperature on some structural and Optical properties of ZnO nanoparticles prepared by a modified Sol gel Combustion Method. Ceram International,37(1):393-398.
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