PHYSICOCHEMICAL ANALYSIS AND CHARACTERIZATION OF BIODIESEL PRODUCTION FROM RICINUS COMMUNIS SEED OIL

  • L. M. Mustapha
  • M. I. Shago
  • R. H. Burhanudden
  • G. Suleiman
Keywords: Biodiesel; Ricinus communis, FTIR; Petroleum ether and Transesterification

Abstract

The global energy concern with the availability of recoverable fossil fuel reserves and the environmental problems caused by those fossil fuels, considerable attention has been given to biodiesel production as an alternative to petro diesel worldwide. In this research, the seed oil of Ricinus communis (castor bean) was investigated for its viability as a feedstock for biodiesel production. The oil was extracted from the seed using petroleum ether .The oil quality characteristics of the seed oil were; Acid values for both Ricinus communis oil  and biodiesel, 4.208 and3.93, and free fatty acids for both Ricinus communis and biodiesel were 1.2408 and 2.508, saponification value (SV) for both Ricinus communis and biodiesel,, 185.0 and 173.16, specific gravity (S.G) for both Ricinus communis and biodiesel, 0.976g/ml and 0.935g/ml. the PH value for both Ricinus communis and biodiesel, 6.67 and 6.8. Refractive index for both Ricinus communis and biodiesel, 1.37 and 1.191, moisture content of seed, 0.052. Colour for both and Ricinus communis oil and biodiesel is brown colour and amber colour, respectively. The oil was transesterified using methanol and concentrated sulphuric acid. And with other investigated oils from the literature and were found to fall within acceptable limits, this implies that Ricinus communis seed oil could be used as diesel in combustion engines in tropical climates like Nigeria.

References

Akpan, U.G., Jimoh, A. and Mohammed, A.D. (2006), Extraction, Characterization and modification of Castor Seed Oil. Leonardo Journal of Sciences, 8: 43-52.

ASTM 2012 ASTM D6751-08: Standard specification for biodiesel fuel (B100) blend stock for distillate fuels Annual Book of ASTM Standards (West Conshohocken, PA: ASTM International).

Amita Nakarmi and Susan Joshi (2014). A Study on Castor Oil and Its Conversion into Biodiesel by Transesterification Method. Nepal Journal of Science and Technology 15(1):45-52

Bello EI, Makanju A (2011)“Production, Characterization and Evaluation of Castor oil Biodiesel as Alternative Fuel for Diesel Enginesâ€, J. Emerging Trends in Engineering and Applied Sciences (JETEAS) 2 (3): 525-530.

Encinar JM, González JF, Sánchez, N, Martínez, G (2010).Synthesis and characterization of biodiesel obtained from castor oil trans-esterification. Fuel Pro. Technol. 91:1530- 1536.

Knothe, G., Dunn R.O., Bagby M.O., (1997) “Biodiesel: the use of vegetable oils and their derivatives as alternative diesel fuels: In Fuels and Chemicals from Biomass, 1st edn. American Chemical Society, New York.

Kyari M.Z.(2008), Extraction and Characterization of Seed Oils, International Agrophysics, 22: 139-142.

Lam M. K., Keat T. L. and Abdul Rahman M. (2010). Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances 28 (2010) 500–518

Mohibbe M.A., Waris, A., Nahar N,M.,( 2005). Prospect and potential of fatty acid methyl esters of some non-traditional seed oil for use as a biodiesel in India. Biomass and Bioenergy ;29:293-302.

Omohu Orijajogun Joyce and Omale Ayegba Clement, Physicochemical Properties and Fatty Acid Composition of Castor Bean Ricinus communis L. Seed Oil, American Journal of Applied and Industrial Chemistry. Vol. 5, No. 4, 2017, pp. 62-65. doi: 10.11648/j.ejb.20170504.11

Omidvarborna,H.,Kane, T., and James,T., 2014 Characterization of particulate matter emitted from transit buses fueled with B20 in idles modes Journal of Environmental Chemical Engineering. 2 (4): 2335– 2342.

Rengasamy Mookan, Krishnasamy Anbalagan , Sundaresan Mohanraj and Velan Pugalenthi (2014). Biodiesel Production from Pongamia pinnata Oil using Synthesized Iron Nanocatalyst,International Journal of ChemTech Research CODEN (USA): Vol.6, No.10, pp 4511-4516.

Soares, I. P., Rezende, T. F.,Silva, R. C., Castro, E. V. R..,Fortes, I. C. P.,( 2008).Multivariate calibration by variable selection for blends of raw soybean oil/biodiesel from different source using Fourier transform infra-red spectroscopy.(FTIR) spectra data. Energy Fuels,22, 2079-2083.

Sheehan J, Dunahay T, Benemann J, Roessler P.( 1998) A look back at the U.S. Department of Energy's Aquatic Species Program — biodiesel from algae. National Renewable Energy Laboratory, Golden, CO;. Report NREL/TP-580–24190

Zhang,Y.,Dub, M. A, McLean D.D., Kates .M (2003). Biodiesel production from waste cooking oil: 1. Process design and technological assessment. Elsevier Journal of Bioresource Technology 89 (2003) 1–16

Published
2021-06-29
How to Cite
MustaphaL. M., ShagoM. I., BurhanuddenR. H., & SuleimanG. (2021). PHYSICOCHEMICAL ANALYSIS AND CHARACTERIZATION OF BIODIESEL PRODUCTION FROM RICINUS COMMUNIS SEED OIL. FUDMA JOURNAL OF SCIENCES, 5(1), 404 - 410. https://doi.org/10.33003/fjs-2021-0501-584