ANALYSIS OF RADIATION SHIELDING PARAMETERS OF PRISTINE AND GADOLINIUM OXIDE DOPED ZINC BOROTELLURITE GLASS SYSTEM
DOI:
https://doi.org/10.33003/fjs-2026-1004-4884Keywords:
Density, Lead-free glass, Radiation shielding properties, Gamma-rays, Mass attenuation, coefficientAbstract
Convectional radiation shielding materials such as lead and concrete present significant toxicity and structural limitations, underscoring the need for safe, high performance glass based alternatives. This paper studies the radiation shielding parameter for the glass of Gd2O3-doped zinc borotellurite glasses, with varying concentrations of Gd2O3 (x = 0.0 to 0.05 mol, coded as S1 to S6). Theoretical calculations using Phy-X and WinXCom software reveal that the glass sample with 5% Gd2O3 (S6) exhibits superior radiation shielding performance, with the highest mass attenuation coefficient (MAC = 0.07623 cm2/g at 0.662 MeV), linear attenuation coefficient (LAC) and effective atomic number (Zeff = 19.10 at 0.662 MeV), as well as the lowest half-value layer (HVL = 1.857 cm at 0.662 MeV) and mean free path (MFP = 2.679 cm at 0.662 MeV) values. The results show a direct correlation between the concentration of Gd2O3 and the material's radiation shielding properties, with S6 demonstrating the best performance. Comparison with lead-free and concrete radiation shielding materials for gamma energies 0.662 MeV, 1.17 MeV and 1.332 MeV reveals that S6 outperforms all compared materials in HVL, MFP and Zeff, highlighting its potential as a superior radiation shielding material. The maximum deviation between MAC value calculated via Phy-X and WinXCom results is 0.088%, confirming the reliability of the calculations.
References
Al-Hadeethi, Y., Ahmad, M., Al-Heniti, S., Sayyed, M., & Rammah, Y. (2020). Rare Earth Co-doped Tellurite Glass Ceramics: Potential Use in Optical and Radiation Shielding Applications. Ceramics International, 46(11), 19198-19208.
Alorin, D. A., Elsafi, M., Almuqrin, A. H., Yasmin, S., & Sayyed, M. I. (2023). Study the Radiation Attenuation Properties of MgO/BariteComposite Ceramics for Photon Shielding Application. Digest Journal of Nanomaterials and Biostructures , 18(3), 1125-1137.
ARPANSA. (2022). Gamma radiation. Radiation Protection and Nuclear Safety Agency. Australian. doi:: https://www.arpansa.gov.au/understanding-radiation/what-is-radiation/ionising-radiation/gamma-radiation
Azuraida, A. (2018). Structural, Optical and Shielding Properties of Bi2O3/BaO-B2O3-TeO2 Doped CeO2 Glass System.
Berger, M., & Hubbell, J. H. (1987). XCOM: Photon cross sections on a personal computer. National Bureau of Standards. Washington, DC (USA). Center for Radiation Research, 1-27.
Çağlar, I., Cengiz, G. B., & Bilir, G. (2021). Gamma Radiation Shielding Properties of Some Binary TelluriteGlasses. Journal of Non-Crystalline Solids,, 574. doi: 10.1016/j.jnoncrysol.2021.121139
Callister, W. D., & Rethwisch, D. G. (2011). Material and Engineering. Wiley: SI version.
Echeweozo, E. O., Ali, M. S., Nwigwe, G. C., Nady, M., Attalla, M. E., Sherkawy, E.-S., & Abdelmonem, A. M. (2025). Theoretical Evaluation of Radiation Shielding and Particle Interaction Feature of ZnOP2O5 Glass Systems Doped withPbO Nanoparticles. SOHAG Journal OF SCIENCE, 10(1), 181-192. doi:10.21608/sjsci.2025315293.1220
Eevon, C., M, K. H., Z, A., & C, A. (2016). Elastic Properties of TeO2 - ZnO-Gd2O3 GlassesUsing Non-Destructive Ultrasonic Technique. Chalogenide Letters, 13(6), 281-289.
Effendy, N., Zaid, M. H., H. Sidek, A. A., Matori, K. A., Mahmoud, K. A., & Sayyed, M. I. (2021). Influence of ZnO to the physical, elastic and gamma radiation shielding properties of the tellurite glass system using MCNP5 simulation code. Radiation Physics and Chemistry. doi:10.1016/j.radphyschem.2021.109665
El-Kameesy, S. Y., El-Ghany, S. A., El-Hakam Azooz, M. A., & El-Gammmam, Y. A. (2013). Shielding Properties of Lead Zinc Borate Glasses. World Journal of Condensed Matter Physics, 3(4), 198–202. doi:10.4236/wjcmp.2013.34033
El-Mallawany, R. (2002). Tellurite Glasses HANDBOOK. USA: CRC Press Inc, Boca Raton, FL.
Gamal, R., Salama, E., Hassan, E., El-Nashar, D., Assem, B., & Ehab, M. (2023). Gamma Attenuation and Mechanical Characteristics of a Lead/NBR/SBR Rubber Composite with Black Nanocarbon Reinforcement. Sustainability, 15(2165), 1-17. doi:10.3390/su15032165
Hasnimulyati, L., Hlimah, M. K., Abdul, H. S., Ishak, M., Azuraida, A., & Nazrin, S. N. (2021). Structural Properties of Cerium Oxide Doped Zinc Borotellurite Glass. Gading Journal of Structural and Technology, 4(2), 58-65.
Hatice, Y. A. (2024). A Study on the Effect of Addition Li, Na, and K on the Radiation Shielding Capabilities of B2O3-TeO2-ZnO-PbF2-Er2O3 Glass Structure. Journal of Science and Engineering, 24, 789-797.
Jamal, N., Natasha, M., Aida, N., & Amin, B. (2020). Tungsten-based Material as a Promising New Lead-free Gamma Radiation Shielding Material in Nuclear Medicine. Physica Medica, 78, 48-57. doi:10.1016/j.ejmp.2020.08.017
Kavaz, E., Ekinci, N., Tekin, H. O., Sayyed, M. I., Aygün, B., & Perişanoğlu, U. “. (2019). Estimation of gamma radiation shielding qualification of newly developed glasses by using WinXCOM and MCNPX code. Progress in Nuclear Energy, 115, 12-20. doi:10.1016/J.PNUCENE.2019.03.029
Klingberg, F. (2009). Cability to Determine Shielding Around Radioactive Substances using Gamma Ray Spectrometry Diploma Thesis.
Matori, K. A., Sidek, H. A., Zaid, M. H., & Singh, V. P. (2017). Comprehensive study on physical, elastic and shielding properties of lead zinc phosphate glasses. Journal of NonCrystalline Solids, 457, 97-103. doi:10.1016/jncrysol.2016
Roberts, P. B. (2003). Encyclopedia of Food Science and Nutrition. 3390. doi:10.1016/B0-12-227055-X/00655-6
Rozi, N. F., L, H., & A, A. (2025). Simulated Radiation Shielding Parameter for Energy 1keV-100GeV of Lead-Freeborotellurite Based Glass for Nuclear Medicine Applications. Chalcogenide Letter, 22(1), 57-76.
Rusni, N. A., Hasnimulyati, L., & Azurriada, A. (2004). Theoretical Ionizing Radiation Shielding Parameters of Thulium Doped Zinc Borotellurite Glass. E3S web Conferences, 481, 1-16. doi:10.1051/e3sconf/20248103009
Rusni, N. M., Azuraida, A., Wan, Y. W., Nor, A. A.-M., & Nurazlin, A. (2024). Mechanical Properties of Thiulium-doped Bismuth Borotellurite Glass via Nanoindentation for Lead-FreeRadiation Shielding Application. Journal of Integrated Engineering, 16(6), 206-215.
Saheb, M. S., Vijay, R., Rao, P. V., Ramesh, P., Chandrakala, B., Prasad, P., & Raju, G. (2018). Result Physics, 11, 780-786.
Salama, E., Abeer, M., & G, M. Y. (2019). Gamma Radiation and Neutron Shielding Properties of Transparent Alkali Borosilicate Glass Containing Lead. Journal of Physics and Chemistry of Solid, 131, 139-147.
Sallam, O. I., Mohamed, A. K., Taha, A. A., Ahmed, A. E.-S., & Eman, Y. F. (2025). Determination of Some Optical, Structural and Radiation Shielding Properties of Waste glass From Cathode Ray Tube. Silicon, 1-14.
Sallam, O., Madbouly, A. M., Moussa, N. L., & Abdel-Galil, A. (2021). Impact of Radiation on CoO-doped Borate Glass: Lead-free Radiation Shielding. Applied Physics A: Material Science & Processing, 128(70), 69-86.
Sayyed, M. I. (2021). Experimental and Theoretical Study of Radiation Shielding Features of CaO-K2O-Na2O-P2o5 Glass Systems. Materials, 14(14). doi:10.3390/ma14143772
Singh, S., Kaur, R., Rani, S., Sidhu, B., & S. (2021). Physical, structural and nuclear radiation shielding behaviour of xBaO(0.30x)MgO0.10Na2O0.10Al2O30.50B2O3 glass matrix. Materials Chemistry and Physics, 276, 125415. doi:10.1016/j.matchemphys.2021.125415
Teresa, E. P., Naseer, K. A., Marimuthu, K., Alorani, H., Aljawhara, H. A., & Sayyed, M. I. (2021). Optical Properties and Radiation Shielding Studies of Europium Doped Modifier Reliant Multi Former Glasses. Optik-International Journal for Light and Electronic Optics, 1-13. doi:10.1016/j.radphyschem.2o21.109741
Udiba, U. U., Ekom, R. A., & Ekpo, E. A. (2019). Soil Lead Concentrations in Dareta Village, Zamfara, Nigera. Journal of Health & Pollution, 9(23). doi:10.5696/2156-9614-9.23.190910
Umeh, C. D., Agwu, K. K., Okoye, C. M., Ahia, C. C., & Ikegbu, G. O. (2021). Characterization of the radiation shielding properties of fired lead sample for X-ray shielding applications. Progress in Nuclear Energy, 137, 103765. doi:10.1016/j.pnucene.2021.103765
Watter, H. (2025). AComperehensive Study on the Effect of BaSO4 on Gamma-Ray Shielding Properties of B2O3-CaO-Na2O-SiO2 Glass System, a Comparative Evaluation Using Phy-X/PSD and XMuDat Program. University of Thi-Qar Journal of Science (UTJsci), 12(1), 133-140.
Downloads
Published
Issue
Section
Categories
License
Copyright (c) 2026 Reuben Abraham Solomon, Oluwatosin Mary Kayode

This work is licensed under a Creative Commons Attribution 4.0 International License.