PHOTODEGRADATION OF METHYL RED USING Cd-Al/C LAYERED DOUBLE HYDROXIDE CATALYST
Abstract
This paper evaluate the degradation of Methyl Red using cadmium aluminum carbon (Cd-Al/C) catalyst under visible light irradiation. The catalyst was successfully prepared from cadmium fluoride (CdF2), aluminium chloride (AlCl3), and rice husks activated carbon, and then characterized by using X-ray Diffraction (XRD), Scaning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) techniques. The peaks at 23.4 and 35.5 in the XRD result confirmed the presences of LDH. The effect of contact time, catalyst dosage, pH and initial concentration, on the photodegradiation of Methyl Red were investigated. The experimental results showed that after 100 min visible light irradiation, the percentage degradation using 200 mg Cd-Al/C, pH 7 and 3 ppm Methyl Red concentration reached to 83.80%. For kinetics studies the data obtained were analyzed using pseudo first order and pseudo second order kinetic models. From the linear regression coefficient values the data were found to be best fitted to pseudo second order kinetics. The results revealed that the Cd-Al/C show good catalytic activity
References
Anitha P and Auguestine A., (2014). Photocacatalytic degradation of Alizarin Red S and Bismarck Brown R using TiO2. Phocatalyst Journal of Chemistry and Applied Biochemistry (1) 1-7
Ayawei, N, Angaye S. S. and Wankasi, D (2017). Mg/Fe Layered Double Hydroxide as a Novel Adsorbent for the Removal of Congo red, International Journal of Applied Science and Technology (7) 2-9.
Cavani, F. Trifiro, A. Vaccari, (1991) Hydrotalcite-type anion clays: preparation, properities and applications, Catalalysis Today (11)173-180.
El-Gain L., Lakarami M., Sebbar E., and Maghea A. (2009). Removal of Indigo Carmine dye From Water Mg-Al-CO3 Calcined Layered Double Hydroxide, Journal of Hazard Material (161) 624-632.
Habino T. and Kobayashi M. (2005). Determination of Layered double Hydroxide in water, Journal of Material Chemistry (15) 653-656.
Khan, S. B., Khan, S. A. & Asiri, A. M. (2016). A fascinating combination of Co, Ni and Al nanomaterial for oxygen evolution reaction. Applied surface sciences (370)445–451.
Li J., S. Liu, and J. Wang (2008). Adsorption and degradation of the cationic dyes over Co doped amorphous mesoporous titania-silica catalyst under UV and visible light irradiation, Microporus Meroporous Material 115(3) 416-425.
Majewski P. J. (2007). Removal of organic matter in water by functionalized self-assembled monolayers on sili¬ca, Separation and Purification Technology (57) 283–288.
Martin M. J., A. Artola, M.D. Balague and M. Rigola (2003). Activated carbons developed from surplus sewage sludge for the removal of dyes from dilute aqueous solutions, Chemical Engineering Journal (94) 231–239.
Parida K. M. and Mohapatra L. (2012) Carb.onate intercalated Zn/Fe layered double hydroxide: A novel photocata¬lyst for the enhanced photo degradation of azo dyes, Chemical Engineering Journal (179) 131–139.
Parida, K. M., Baliarsingh, N., SairamPatra, B. and Das J. (2006). Copper Phthalocyanine Immobilized Zn/Al LDH as Photocatalyst under Solar Radiation for Decolorization of Methylene Blue, Journal of MolecularCatalysis A: Chemical (267) 202-8.
Ren N., Charlton J. and Alder P.N. (2007). The flare gene, which encodes the AIPI protein Dros Phila, function to regulate F-action disassembly in popular epidermis cells Genetics 176 (4) 2223-2234.
Shahid A. K., Sher B. K., and Abdullahi M. A. (2016).Layered double hydroxide of Cd-Al/C for the Mineralization and De-coloration of Dyes in Solar and Visible Light Exposure.Scientific report, (10) 1038-1045.
Shankar M.V.; KK Cheralathan; B Arabindoo; M Palanichamy; V Murugesan(2004). Enhanced photocatalytic activity for the destruction of monocrotophos pesticide by TiO2, Journal Molecular Catalysis A Chemical. (223) 195-200.
Singh N.k., Sandip S. and Anjali P. (2014). Methyl Red Degradation under UV illumination and catalytic action of commercial ZnO, Journal of Desllination and Water Treatment (56) 1066-1076.
Sumanjit K. Seema R. and Rakesh K.M. (2006). Adsorption Kinetics for Removal of the Hazardous Dye Congo Red by Biowaste material as adsorbents, Journal of Chemistry (10) 1155-1160.
Tanaka T., S. Nishimoto, Y. Kameshima, J. Matsukawa, Y. Fujita, Y. Takaguchi, M. Matsuda, M. Miyake, (2010) " A novel nanocomposite material prepared by intercalating photoresponsivedendrimers into a layered double hydroxide, Journal solid state chemical (183) 479-485.
Thota S., Siva R. T and Sreedhar B. (2014). Visible light photocatalytic Degradation of Methyl Red with Codoped Titanium, (1155) 9624-9628
Zhang X.H., Axton J.M., Drinjakovic J., Lorenz L White-Cooper H. and Renault A.D. (2004). Spatial and Temporary Control of Mitotic Cyclins by the Gnu regulator by the embryonic mitosis in Drosophila. Journal of Cell Sciences. (16) 3571-3578.
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