ENHANCED PHYSICO-MECHANICAL AND THERMAL PROPERTIES OF WASTE HDPE/LDPE BLENDS REINFORCED WITH Borassus aethiopum FIBRES
DOI:
https://doi.org/10.33003/fjs-2025-0905-3428Keywords:
Borassus aethiopum, Composites, Dynamic mechanical analysis, Physical and mechanical propertiesAbstract
This study evaluated the effects of Borassus aethiopum fibre (BAP) on waste HDPE-LDPE blends. The (Borassus aethiopum fibre (BAP) on waste HDPE-LDPE) materials were compounded on a Two Roll Mill and compression moulding machines. Properties such as density, water absorption, tensile strength, elastic modulus, flexural strength and hardness values were evaluated using standard procedures. The materials were further subjected to dynamic mechanical properties test in order to evaluate the influence of BAP fibre incorporation on the storage modulus, loss modulus and damping parameter of waste HDPE-LDPE blends. Optimal mechanical properties (tensile strength = 77.5 MPa, stiffness = 3.5 GPa) were achieved at 40 wt% BAP loading. This composition has corresponding minimal water absorption of 0.45 % after 240-hrs immersion period at room temperature. Similarly, dynamic mechanical properties results indicated that the storage modulus and load bearing capability of were found to be maximum (1.2 GPa) for a composite with 40 % weight of BAP fibre compared (to 400 MPa of the unreinforced) while a decrease in loss modulus was observed with increase in temperature and frequency. This indicates that incorporation of BAP fibre into waste HDPE-LDPE blends improved its physical, mechanical and dynamic mechanical properties with these properties increasing with the weight percentage of BAP incorporated up to 40 % and a sudden decrease at 50 % weight of BAP.
References
Adefemi, S. O., Bamgboye, O. A. and Awomeso, J. A. (2016). Evaluation of leachate contamination of groundwater sources in an open dumpsite in Nigeria. Environmental Monitoring and Assessment. 188(2), 105.
Adewuyi, G. O. and Opasina, M. F. A. (2010). Physicochemical and heavy metals assessment of leachates from Aperin Abandoned Dumpsite in Ibadan city, Nigeria. E-Journal of chemistry. 0973-4945;7(4). 1278-1283 CODEN ECJAO https://unve-journals.net.
Adeyemi-Ale, O. A., Anifowoshe, A. T. and Abdulkareem, S. I. (2018). Ecotoxicological assessment of leachate from Amilegbe Dumpsite, Ilorin, Nigeria using Clarias gariepinus, and Allium cepa. Agrosearch. 18(2). 59-71. https://dx.doi.org/10.4314/agrosh.v1812.5 .
Agbeshie, A. A., Adjei, R.., Anokye, J. and Banunle, A. (2020). Municipal waste dumpsite: Impact on soil properties and heavy metal concentrations, Sunyani, Ghana. Scientific African. https://doi.org/10/1016/j.sciaf.
Akaeze, C.S. (2001). Solid waste analysis, characterization and management along Abak/Ikot Ekpene Roads of Uyo metropolis. A research project of Chemistry/Biochemistry Department, University of Uyo, Nigeria. 7-15.
Akinbile, C. O., Nwankwoala, H. O. and Oyewole, N. O. (2017). Impact of municipal solid waste dumpsites on surrounding soil quality in Ibadan metropolis, Nigeria. Journal of Environmental Science and Engineering. 6(12), 533 546.
Akwa, V. L., Binbol, N. C., Samaila, K. I. and Markus, N. D. (2007). Geographical perspective on Nasarawa State. A publication of Geography Department, Nasarawa State University, Keffi, Nigeria. .8-15.
Anake, W.U., Adie, G.U. and Osibanjo, O. (2009). Heavy metals pollution at municipal solid waste dumpsites in Kano and Kaduna States in Nigeria. Bull. Chem. Soc. Ethiop. 23(1). ISSN 1011-3924. 281-289.
Anmani, S. and Gandhimathi, R. (2013). Assessment of heavy metal contamination in soil due to leachate migration from an open dumping site. Appl. Water. Sci 3: 193-205. DOI.10.1007/s13201-012.0072-012.0072-z.
Anthony, E., Isaa, E. and Derrick, A. (2021). modeling of total dissolved solids in water supply systems using regression and supervised machine learning approaches. Applied Water Science https://doi.org/10.1007/s.13201-020-01352-7.
Anzene, J. S. and Malu, P. S. (2014). Determination of levels of eight trace metals in ground water sources within and around Lafia metropolis. International Journal of Innovative Science, Engineering and Technology. 1(5). www.ijiset.com. 219-237
AOAC. (2013). Official Methods of Analysis of the Association of Official Analytical Chemists. 17th Ed. Association of Official Analytical Chemists
Aremu, M. O., Atolaiye, B. O. and Labaran, L. (2010). Environmental implication of metal concentrations in soil, plant foods and pond in area around the derelict Udege Mines of Nasarawa State, Nigeria. ISSN 1011-3924. Bull.Chem.Soc.Ethiop 24(3). 351-360
Aremu, M. O., Atolaiye, B, O., Gav, B. L., Opaluwa, O. D., Sangari, D. U. and Madu, P. C. (2011). Heavy metal concentrations in sediments and water from Rivers Doma, Farinruwa and Mada in Nasarawa State, Nigeria. Journal of Environmental Chemistry and Ecotoxicology. ISSN. 2142-226X. 242-249.
Arshi, I. and Khan T. I. (2018). Analysis of soil quality using physicochemical parameters with special emphasis on Fluoride tone selected sites of Sawai Madhopier Tehsil, Ajasthan. International Journal of Environmental Sciences and Natural Resources. 12(5).
Augustine, K. A. and Morounfolu, A. U. (2014). Radiological safety assessment and determination of heavy metals in soil samples from the waste dumpsites in Lagos and Ogun states, South-Western Nigeria. Journal of Radiation Research and Applied Sciences. https://doi.org/10.1016/www.elsevier.com/locate/jrras. 149-153
Ayih, S. O. (2003). Nasarawa State, Past and Present. .2nd Ed. 1-10.
Badmus, B. S., Ozebo, V. C., Idowu, O. A., Ganiyu, S. A. and Olurin, O. T. (2014). Physicochemical properties of soil samples and dumpsite environmental impact on ground water quality in South Western Nigeria. The African Review of Physics. 9. 0015
Banki, T. C., Sani, Y., Ishaya, K. S. and Shittu, W. J. (2019). Analysis of urban land use and land cover change for sustainable development. A case of Lafia, Nasarawa State, Nigeria. Journal of Geographic Information System. https://doi.org/10.4236/jgis.2019.113021.
Benedicta, Y. F. M., Emmanuel A., Dzidzo, Y. T. and Frank, N. (2017). Heavy metals concentration and distribution in soils and vegetation at Korle Lagoon area in Accra, Ghana. Cogent Environmental Science. 3:1405887. https://doi.org/10.1080/23311843.2017.1405887. 6(2). 16-29
Beniah, O. I. and Christian, E. E. (2020). Pollution and health risks assessment of nitrate and phosphate concentrations in water bodies in South Eastern, Nigeria. Environmental Advances. www.Elsevier.com/locate/envadu.
Bernard, G. M. V. (2006). Chemometrics General Introduction and Historical Development. Research Gate. 1 -10
Besufekad, M., Alemayehu, H. and Wuhib, Z. (2020). Assessment of effect of solid waste dumpsite on surrounding soil and River Water Quality in Tepi Town, South West Ethiopia. Journal of Environ and Public Health. https://doi.org/10.1155/2020/5157046. 1-9
Binbol, N. L. and Markus, N. D. (2000). Geography of Nasarawa State. A Study of Flora and Fauna. 1-6.
Chessed, G., Sakiyo, D. C., and Yako, A. B. (2018). Concentration of heavy metals in soil around Dumpsites in Jimeta and Ngurore, Adamawa State, Nigeria. Nigerian Annals of Pure and Applied Sciences. Maiden edition. 105-112.
Cyril, N. and Difference, O. (2012). An Investigation of temperature variation at soil depths in parts of Southern Nigeria. American Journal of Environmental Engineering. 2(5): 142-147. DO1: 10.5923/j.ajee:2012.0205.05
Dupuy, N. and Douay, F. (2001). Infrared and chemometrics study of the interaction between heavy metals and organic matter in soils. Spectrochimica Acta part A (57) (2001). 1037-1047.
Ebong, E. A., Akpan, M. M. and Mkpenie, V. N. (2008). Heavy metal contents of municipal and rural dumpsite soils and rate of accumulation by Carica Papaya and Triangulare in Uyo, Nigeria. E-Journal of Chemistry ISSN: 0973-4945. https://www.e.journals-net.Elsevier.
Ebuga, E. A., Angbo, Y. B. and Obadiah, B. (2021). Impact of heat island on human comfort in Lafia urban area in Nasarawa State, Nigeria. International Journal of Research on Innovation in Applied Sciences (URIES) VI(XI). ISSN 2454 6194.
Edieme, V. F. and Umoetok, S. B. A. (2017). Concentration of heavy metals in soils at the municipal dumpsite in Calabar metropolis. Asian Journal of Environment & Ecology. 3(2): ISSN:2456-690x. 1-11. Doi:10.9734/AJEE/2017/34236.
Ekeu-Wei, I. T., Azuma, K. I. and Ogumuyiwa, F. B. B. (2018). Nigerian Journal of Technology (NIJOTECH) 37(1) ISSN:0331-8443.www.nijotech.comhttp://doi.org/10.4314/njt.v.37:1.36.
Franklyn. O. O., Kelechi, C. L., Paul, C. C., Andrew, W. V. and Christian, E. E. (2020) Pollution profile and ecological risk assessment of heavy metals from dumpsites in Ome, Rivers State, Nigeria. Chemistry Africa. https://doi.org/10.007/s 42250-20-00198-5.
Gary, W. V. and Stephen, J. D. (2000) Environmental chemistry, a global Perspective. 386-435.
Henry, O. A., Adedotun, T. A., Abiodun, S. A., Oluwatoyosi, O. S. and Biola, K. B. (2017). Impact of dumpsites on the quality of soil and groundwater in satellite towns of the Federal Capital Territory, Abuja. J. Health Pollut 7(14):15-22. Doi:10.5696/2156-9614-7.14.15.
Hooi-Hoon, A., Ee-Lin, L., and Hui-Seong, C. (2004). Determination of mercury by cold vapor atomic absorption spectrophotometer in Tongkat Ali preparations obtained in Malaysia. Sege Journals. Doi: 10.1080/10915810490269654
Isa, B.K., Syed, N.T. and Mohammed, A. H. D. (2018). A chemometric approach to the distribution and source identification of Heavy metals in Tannery contaminated soil. Internal Journal of Theoretical and Applied Sciences.10(1), 01-08.
Iwegbue C. M. A., Nwajei; G.E., Overah, C.L. and Ogala, J.E. (2010). Determination of trace metal concentrations in soil properties of municipal waste dumpsites in Nigeria. Environ Geochem Health. 32. 415-430. Doi. 10.1007/s10653-010-9285-y.
Iwegbue, C. M. A., Enuh, F. N., Isirimah, O. N. and Egun, A. C. (2007). Fractionation, characterization and speciation of heavy metals in composts and compost amended. Soils, Afr. J. Biotechnol. 6(2).067-078.
Iyana, W. A. and Edori, O. S. (2020). Assessment of physical quality of leachates from dumpsites in Port Harcourt and environs. Rivers State, Nigeria. Ecologia. Doi:10.3923/ 20-29.
Lekan, O.A., Amos, A. O. and Abel, O. J. (2020). Evaluation of soil court amination status around municipal waste dumpsite using contamination indices, Soil-quality guidelines, and multivariate statistical analysis SN Applied Sciences 2:1864/https://doi.org/10.1007/s42452-020-03678-4.
McMurry, J., Castellion, N., Ballantime, D. S., Hoeger, C. A. and Peterson, V. E. (2010). Fundamentals of General, Organic and Biological Chemistry, 6th Ed. Practice Hall. 67-87.
Mekonnen, B., Haddis, A. and Zeine, W. (2020). Assessment of the effect of solid waste dump site on surrounding soil and river water quality in Tepi Town, Southwest Ethiopia. Journal of Environmental and Public Health. Article ID 5157046 https://doi.org/10.1155/2020/5157046.
Mendham, J., Denney, R. C., Barnes, J. D. and Thomas, M. (2000). Vogels Textbook of Quantitative Chemical Analysis. 6th Edition, Prentice Hall, 117 169.
Musa, J. J., Bala, J. D., Mustapha, E. T., Akos, M. P., Yerima, Y. I. and Daniel, E. S. (2020). Organic matter and heavy metals leachate effect on soils of selected dumpsites in selected North Central States of Nigeria. Arid Zone Journal of Engineering, Technology, and Environment. Vol. 16 (1): 193-210
Nabil, N., Merc, E. B., Charbel L., Wissem, M., Issam, B. and Nasir, K. (2014). The influence of soil Properties on the Development of Cephalcia tannourinensis Chevin (Hym. Pamphiliidae) Infesting the Cedar Forests in Lebanon. Academic/journals 13 (47). 4381 http: //www. academicjournals.org/A/ B.
Natalia, R. and Antonio. G. (2011). Determination of mercury distribution inside spent compact fluorescent lamps by atomic absorption spectrophotometer. Waste Management. doi. 10. 1016/j. wasman.2011.12001
National Population and Housing Census. (2006). Federal Republic of Nigeria Official Gazette.
Ngoc, H.H., Anh, M.C., Kim, T.T.N. and Chi, H.L. (2022). A novel mathematical modeling for simulating the spread of heavy metals in solid waste landfills Environmental Engineering Research. 27(3); 210007.Doi:https/doi.org/10.4491/eer.2021.007. 1-16.
Nicholas, J. H. (2007). Fundamentals of Algorithms. Society for Industrial and Applied Mathematics.
Nkwocha, A. C., Ekeke, I. C., Kamalu, C. I. O., Oghome, P. I., Osoka, E. C. and Nkuzinne, O. C. (2018). Kinetic modelling of Vitamin C degradation in selected fruits under market storage conditions. International Journal of Environment, Agriculture and Biotechnology 5(3). https://dx.doi.org./10.22161/ijeab/3.57 1618-1627.
Nnorom, I. C. and Osibanjo, O. (2021). Evaluation of heavy metal pollution and human health risk assessment in soils around informal electronic waste recycling workshops in Nigeria. Journal of Environmental Monitoring and Assessment. DOI: 10.1007/s10661-021-09267-5.
Obaliagbon, O. K. and Olowoyoba, G. B. (2006). Distribution of some heavy metals in leachates from a municipal waste dumpsite. Paper presented at the International Conference on Engineering Research and Development, University of Benin, Benin city.
Obasi, M. A., Akubugwo, E. I. U. and Glory, O. (2012). Assessment of physico-chemical properties and heavy metals bioavailability in dumpsites along Enugu-Port Harcourt Expressways, South-East, Nigeria. Asian Journal of Applied Sciences, 5:342-356 DOI. 10.3923/ajabs.2012.342.356 URL: https://scialert.net/abstarct/?doi=ajabs.2012.346.356. 342-356.
Oketola, A. A. and Akpotu, S. O. (2015). Assessment of solid waste and dumpsite leachate and topsoil- Journal of Chemistry and Ecology. 31 (2). https://doi.org/10.1080/02757540.2014.907280. 134 - 146.
Olayinka, O. O., Akande, O. O., Bangbose, K. and Adetunji, M. T. (2007). Physicochemical characteristics and heavy metal levels in soil samples obtained from selected anthropogenic sites in Abeokuta, Nigeria. J.Appl.Sci.Environ.Manage. ISSN 1119- 1(5).883-891.
Oluwatosin, S. S., Olubode, O. A. and Olutayo, S. S. (2020). Seasonal variations of heavy metals concentrations and pollution assessment of major dumpsites in Ilisan-Remo, Nigeria. Environmental Health Engineering and Management Journal 7(3) 193-202.
Oluyemi, E. A., Feuyit, G., Oyekunle J. A. O., and Ogunfowokan, A. O. (2008). Seasonal Variations in Heavy Metal Concentration in Soil and Some Selected Crops at a Landfill in Nigeria. Africa Journal of Engineering Science and Technology. 2 (5) 089-096. http://www.academicjournals.org/Ajest.
Opaluwa O. D., Aremu, M. O. Ogbo, L. O., Abiola, K. A., Odiba, I. E., Abubakar, M. M., and Nweze, N. O. (2012). Heavy metal concentrations in soils, plant leaves and crops grown around dumpsites in Lafia Metropolis, Nasarawa State, Nigeria. Advances in Applied Science Research. 3(2) ISSN. 0976-8610. www.pelagiaresearchlibrary.com. 780-784.
Orodu, V. E. and Morokowei, R. (2022). Determination of nitrates, sulphates and phosphates in soil of Ogbiri and Adagbabiri Farmlands in Bayelsa State; Nigeria. Plant Nutrition and Soil Science. International. DOI: 10.239 77/PNSSI.2022.010101. 1(6) ISSN 2616-1745.
Pueyo, M., Mateu, J., Rigol, A. and Rauret, G. (2008). Use of the modified BCR three-step sequential extraction procedure for the study of trace element dynamics in contaminated soils. Environmental pollution. 2(15) 330-340
Rasmos, B. (2003). Multivariate calibration: what is in chemometrics for the analytical chemist? Analytica Chimica Acta. 500. 185-194 doi: 10:1016/50003-2670 (03)00681-0. www.sciencedirect.com.
Rasool, B. M., Jianguo, L., Dongbei, Y. and Yongfeng, N. (2007). Biodegradation of organic matters from mixed unshredded municipal solid waste through air convection before landfilling. Journal of the Air & Waste Management Association. Doi:10.1080/10473289.2007.10465296. ISSN:1096-2247
Raymond, A. W. and Felix, E. O. (2011). Heavy metals in contaminated soils. A Review of Sources, Chemistry, Risks and Best Available Strategies for Remediation. International Scholarly Research Network. Article ID 402 647. Doi:10.5402/2011/402647. 1-20.
Ruth, O. E. U., Wisdom, C. U. and Moses, O. E. (2021). Quantitative analysis of physical and chemical attribute of soil around power line dumpsite at Boji-Boji Owa, Delta State, Nigeria. World News of Natural Sciences. www.worldnewsnaturalsciences.com.
Saanu, E. K. and Josephine, B. E. (2017). Toxicity assessment using Clarias gariepinus and microbial characterization of leachate from Akomo Municipal Solid Waste Landfill, Igbemo Ekiti, Ekiti State, Nigeria. Journal of Environmental Pollution and Human Health, 5(3), 83-88. DOI: 10.12691/jephh-5-3-1.
Sabyasachi, R., Ajay, K., Sarkar, P. K; Manish, K; and Mishra, P. M; (2013). Application of chemometric methods for assessment of heavy metals pollution and source apportionment in Riparian zone soil of Ulhas River estuary, India. International Journal of Environmental Sciences. 3(5), 2013.ISSN 0976-4402. 1-12. Doi:10.6088/ijes.2013030500019.
Saheed, I. O., Azeez, S. O., Jimoh, A. A., Obaro, V. A. and Adepoju, S. A. (2020). Assessment of some heavy metals concentrations in soil and groundwater around refuse dumpsite in Ibadan Metropolis, Nigeria. Nigerian Journal of Technology (NIJOTECH).1(39). 301-305.http://dx.doi.org/10.4314/njit.v39i.33
Saida, M. C., Arezki, D., Djaber, T. and Rym, S. (2019). A study of the impact of municipal solid waste (MSW) on some soil physiochemical properties. The case of the landfill of Ain-El-Hammam Municipality, Algeria. Applied and Environmental Soil Science ID 3560456 https://doi.org/10.1155/2019/3560456. 185-195
Sanayei, Y., Ismail, N. and Talebi, S. M. (2009). Determination of heavy metals in Zayandeh Road River, World Applied Sciences Journal 6(9) 1209-1214.
Sani, U., Uzairu, A. and Abba, H. (2012) Physicochemical parameters of soil in some selected dumpsites in Zaria and its Environs. Chemsearch Journal 3(1): ISSN: 2276 707X. l-6.
Schreier, O. and Sperner, E. (2011). Introduction to Modern Algebra & Matrix Theory.2nd Edition. Dover publications
Soper, R. and Smith, T. S. (1990). Biology: An integrated approach. Macmillan Publishers. 54-60
Spela, K. U., Nina, F., Matejka, T. and Aleksandra, L. (2013). Sensing heavy metals using mesoporous-based optical sensors, Journal of Nanomaterials https://www.-hindawi.com/journals/jnm/2013/501.
Suleiman, R., Jimoh, I. and Aliyu, J. (2017). Assessment of soil physical and chemical properties under vegetable cultivation in Abuja Metropolitan Area, Nigeria. Zaria Geographer. 1(24).
Suleiman, R. M., Raimi, M. O. and Sawyer, H. O. (2019). A deep dive into the review of national environmental standards and regulations enforcement agency (NESREA) Act. International Research Journal of Applied Sciences. 1(4). ISSN: 2663-5577
Sylvester, C. I., Sunday, E. B. and Elijah, I. O. (2017). Assessment of pollution load indices of Heavy Metals in cassava mill Effluents of contaminated Soil: A case study of small-scale processors in a rural community in the Niger Delta; Nigeria. Bioscience Methods. 8 (1), 1-17.
Tantemsapya, N., Naksakul, Y. and Wirojanagud, W. (2011). Mathematical modeling of heavy metals contamination from MSW landfill site in Khonkaen, Thailand. Water Science & Technology. Doi.10.2166/wst.2011.751. 1836-1842.
Thelma, A., Boakye S., Lawrence, S. B., Matt, D. and Godfred, D. (2020). Distribution of heavy Metals in Soils from abandoned dumpsites in Kumasi, Ghana. Scientific African. https://doi.org/10.1016/j.sciaf.
Torres Bejarano, F., Couder-Castanada, C., Ramirez-leon, H., Hernandez Gomez, J. J., Rodriquez Cueves, C., Herrara Diaz, I. E. and Barrios - Pina, H. (2019). Numerical modelling of heavy metal dynamics in a river-lagoon system. Mathematical problems in Engineering. Article ID 8485031, 1- 24.https://doi.org/10.1155/2019/848503/
Valentine, I. O. and Victor, C. E. (2021). Identification of heavy metals source within selected active dumpsites in South Eastern Nigeria. Environ Anal health Toxicol 36(2). E2021008. Doi.10.5620/eaht2021008.
Vincent, K. N., Ebenezer, K. H. and Smile, K. A. (2012). Assessment of the impact of solid waste dumpsites on some surface water systems in the Accra Metropolitan Area, Ghana. Scientific Journal of Resource and Protection. (4) 605-650.
Vhahanquele, M. and Khethutshelo L. M. (2018). Environmental contamination of heavy metals DOI: 10, 5772/Intechopen. 76082. 1-23.
Vodyanitskii, Y. N. (2016). Standards for the contents of heavy metals in soils of some states. Annals of Agrarian Science. (14) .http://www/journals.elsevier.com/http://dx.doi.org/10.1016/j.ansci. pp.257-263.
WHO/FAO. (2007). Joint FAO/WHO Food Standard Programme Codex Alimentarius Commission 13th session, report of the thirty-eight session of the codex committee on food hygiene, Houston.
Wunzani, D. K., Dauda, M. S., Wyasu, G. and David, D. A. (2020). Assessments of physicochemical properties and heavy metals content in soils from selected solid waste dumpsites in Kaduna metropolis, Kaduna State. Science World Journal. 15(1) 76-79.
Wodaje, A. and Alemayehu, A. (2014). Analysis of selected physicochemical parameters of soils used for cultivation of Garlic (Allium Sativum L.) Science, Technology and Arts Research Journal. DO1: http://dx.doi.org./10.4314/star. v3:443(4): 29-35.
Yahaya, M. I., Mohammed, S. and Abdullahi, B. K. (2009). Seasonal variations of heavy metals concentration in Abattoir Dumping Site Soil in Nigeria. Appl.Sci.Environ.Manage. 13 (4) 9-13. JASEM ISSN 1119 808362.
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