DETERMINATION OF PAHS IN UNDERGROUND WATER USING GC-MS AND GC-FID IN OSUN STATE, SOUTHWEST NIGERIA

Authors

  • T. Faraday Ediagbonya
    Department of Chemical Sciences, Olusegun Agagu University of science and Technology, Okitipupa
  • Joseph I. Uche
    University of Delta, Agbor
  • Doris D. Olojo

Keywords:

GC-MS, GC-FID, Polycyclic aromatic hydrocarbons, Underground water contamination, Water quality assessment

Abstract

Contamination of underground water by polycyclic aromatic hydrocarbons (PAHs) poses significant health risks, yet the effectiveness of different analytical methods in detecting these contaminants remains unclear. This study compares the sensitivity of Gas Chromatography-Mass Spectrometry (GC-MS) and Gas Chromatography-Flame Ionization Detection (GC-FID) in analyzing PAH concentrations in borehole and well water in Osun State, Nigeria. Results showed that GC-MS detected a broader range of PAHs (22 compounds) compared to GC-FID (13 compounds), highlighting its higher sensitivity. While GC-FID recorded higher PAH concentrations in borehole samples, GC-MS provided a more precise differentiation of compounds. These findings emphasize the importance of selecting an appropriate detection method to accurately assess PAH contamination in drinking water, which is crucial for environmental monitoring and public health safety.

Dimensions

Abolanle S.A., John A.O.O., Oluwaseyi S.O., Nobanathi W. M. B., Godwin O.O., Olaoluwa R.O. (2017). Determination of polycyclic aromatic hydrocarbon levels of groundwater in Ife north local government area of Osun state, Nigeria, / Toxicology Reports, 4 3948.

Adeniji, A. O., Okoh, O. O., &Okoh, A. I. (2019). Distribution pattern and health risk assessment of polycyclic aromatic hydrocarbons in the water and sediment of Algoa Bay, South Africa. Environmental geochemistry and health, 41, 1303-1320.

Anyakora C.A., Ogbeche K.A., Palmer P., Coker H., Ukpo G., Ogah C. (2004). A screen for Benzo(a)pyrene, a carcinogen: in the water samples from the Niger Delta region, Nig. J. Hosp. Med. 14 (2004) 288293.

Chen H, Gao G, Liu P, Pan R, Liu X, Lu C (2016) Determination of 16 polycyclic aromatic hydrocarbons in tea by simultaneous dispersive solid-phase extraction and liquidliquid extraction coupled with gas chromatographytandem mass spectrometry. Food Anal Methods 9:23742384.

Chih-Feng C., Yun-Ru J., Yee C. L., Shu-L.H., Mei-Ling T., Pei-Pei S., Ravi K., Chiu-Wen C., and Cheng-Di D. (2019), Determination of Polycyclic Aromatic Hydrocarbons in Sludge from Water and Wastewater Treatment Plants by GC-MS, Int. J. Environ. Res. Public Health, 16, 2604.

Dorea, H.S., Bispo. J.R.L., Arago, K.A.S., Chuna, B.B., Navickiene,. S., Alves,j.p.h., Garcia, C.A.B. (2007). Analysis of BTEX, PAHs and metal in the oilfield produced water in the brazil. Microchemical journal, 85(2), 234-238.

Dimitrios T (2023), GC-MS measurement of malondialdehyde (MDA) in clinical studies: Pre-analytical and clinical considerations, Journal of mass Spectrometry and Advances in the clinical Lab 30:10 24. https://doi.org/10.1016/

Duedahl-Olesen L, Navaratnam MA, Jewula J, Jensen A (2015) PAH in some brands of tea and cofee. Polycycl Aromat Compd 35:7490

Ediagbonya, T. F., Omokungbe, O.R., Bagbe ,A. S., Ajibare, O. A., Akinola, T.M., Obebe., F. C. (2024a) An assessment of the risks related to polychlorinated biphenyls (PCBs) in sediments, water, and Prawn (Nematopaleamon Hastatus) in Araromi Beach, Ondo State, Nigeria. Toxic and Environ Health 29;1-16

Ediagbonya, T. F., Francis, S. D., Omotayo-Tomo, M.S.,Oziegbe, F. E., Awojobi, O A (2024b) Risk Assessment and Quantification of Elemental Concentrations in River and Stream in Nigeria . Discover Toxicology.2:;1-16

Fabio I. M., Heronides A.D., Kellydas G.F. (2019). Simultanueous determination of 16 polycyclic aromatic hydrocarbons in groundwater by GC-FID after solid-phase extraction, SN appl. sci 1, 804.

Geiss O, Senaldi C, Bianchi I, Lucena A, Tirendi S, Barrero-Moreno J (2018) A fast and selective method for the determination of 8 carcinogenic polycyclic aromatic hydrocarbons in rubber and plastic materials. J Chromatogr A 1566:1322

Gorji M.E.H., Ahmadkhaniha R, Moazzen M, Yunesian M, Azari A, Rastkari N (2016) Polycyclic aromatic hydrocarbons in Iranian Kebabs. Food Control 60:5763.

Khalili F, Shariatifar N, Dehghani MH, Yaghmaeian K, Nodehi RN, Yaseri M (2021) The analysis and probabilistic health risk assessment of polycyclic aromatic hydrocarbons contamination in vegetables and fruits samples marketed Tehran with chemometric. Glob Nest J 23:112.

Kiani A, Ahmadloo M, Moazzen M, Shariatifar N, Shahsavari S, Arabameri M, Hasani MM, Azari A, Abdel-Wahhab MA (2021) Monitoring of polycyclic aromatic hydrocarbons and probabilistic health risk assessment in yogurt and butter in Iran. Food Sci Nutr 9:21142128.

Li, J., Wu, J., Wang, Y., Wu, Y., & Yang, L. (2022). Determination of polycyclic aromatic hydrocarbons in underground water using GC-FID and GC-MS with improved sensitivity and selectivity. Environmental Science and Pollution Research International, 29(12), 14461-14472.

Maks P, Przyjazny A, Boczkaj G (2018) Hydrophobic deep eutectic solvents as green extraction media for polycyclic aromatic hydrocarbons in aqueous samples. J Chromatogr A 1570:2837

Ogbuagu, D. H., Okoli, C. G., Gilbert, C. L., &Madu, S. (2011). Determination of the contamination of groundwater sources in Okrika Mainland with Polynuclear Aromatic Hydrocarbons (PAHs). British Journal of Environment and Climate Change, 1(3), 90-102

Olajire A., Alade A.O, Adeniyi A.A., Abemiwo O.M. (2007). Distribution of polycyclic aromatic hydrocarbons in surface soils and water from the vicinity of Agbabu bitumen field of southwestern Nigeria, J. Environ. Sci. Health 42 (8) 10431049.

Ogunfowokan, A.O., Asubiojo, O.I. & Fatoki, O.S. (2003). Isolation and determination of polycyclic aromatic hydrocarbon in surface runoff and sediments. Water, air & soil pollution. 147, 245-261

Onydinma, U. P., Aljerf, L., Obike, A., Onah, O. E., & Caleb, N. J. (2021). Evaluation of physicochemical characteristics and health risk of polycyclic aromatic hydrocarbons in borehole waters around automobile workshops in Southeastern Nigeria. Groundwater for Sustainable Development, 14, 100615.

Roudbari A, Nazari RR, Shariatifar N, Moazzen M, Abdolshahi A, Mirzamohammadi S, Madani-Tonekaboni M, Delvarianzadeh M, Arabameri M (2021). Concentration and health risk assessment of polycyclic aromatic hydrocarbons in commercial tea and coffee samples marketed in Iran. Environ Sci Pollut Res 28:48274839. 0

Shariatifar N, Moazzen M, Arabameri M, Moazzen M, Khaniki GJ, Sadighara P (2021) Measurement of polycyclic aromatic hydrocarbons (PAHs) in edible mushrooms (raw, grilled and fried) using MSPE-GC/MS method: a risk assessment study. Appl Biol Chem 64:111.

Teimoori, S., Shirkhanloo, H., Hassani, A. H., Panahi, M., &Mansouri, N. (2023). New extraction of toluene from water samples based on nano-carbon structure before determination by gas chromatography. International Journal of Environmental Science and Technology, 20(6), 6589-6608.

Thamatam, N., Ahn, J., Chowdhury, M., Sharma, A., Gupta, P., Marr, L. C., ...&Agah, M. (2023). A MEMS-enabled portable gas chromatography injection system for trace analysis. Analytica ChimicaActa, 1261, 341209

Ugochukwu, U. C., & Ochonogor, A. (2018). Groundwater contamination by polycyclic aromatic hydrocarbon due to diesel spill from a telecom base station in a Nigerian City: assessment of human health risk exposure. Environmental Monitoring and Assessment, 190(4).

Ukaogo P.O., Loai A.b, Anthony O., Ojah E.O., Nwaogwugwu J.C. (2021), Evaluation of physicochemical characteristics and health risk of polycyclic aromatic hydrocarbons in borehole waters around automobile workshops in Southeastern Nigeria. Groundwater for Sustainable Development, 14 100615.

Published

28-02-2025

How to Cite

DETERMINATION OF PAHS IN UNDERGROUND WATER USING GC-MS AND GC-FID IN OSUN STATE, SOUTHWEST NIGERIA . (2025). FUDMA JOURNAL OF SCIENCES, 9(2), 152-157. https://doi.org/10.33003/fjs-2025-0902-3140

Issue

Vol. 9 No. 2 (2025): FUDMA Journal of Sciences - Vol. 9 No. 2

Section

Research Articles
Copyright & Licensing

FUDMA Journal of Sciences

How to Cite

DETERMINATION OF PAHS IN UNDERGROUND WATER USING GC-MS AND GC-FID IN OSUN STATE, SOUTHWEST NIGERIA . (2025). FUDMA JOURNAL OF SCIENCES, 9(2), 152-157. https://doi.org/10.33003/fjs-2025-0902-3140

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