ESTIMATION OF THE ABUNDANCE AND DISTRIBUTION OF RARE EARTH ELEMENTS IN SOIL AROUND KADUNA REFINING AND PETROCHEMICAL COMPANY USING NUCLEAR TECHNIQUE

  • Michael A. Onoja
  • P. H. Bukar
  • C. U. Omeje
  • A. M. Adamu
Keywords: INAA, REE, abundance, soil, Kaduna Refinery

Abstract

Instrumental neutron activation analysis (INAA) technique was used to investigate the abundance and distribution of rare earth elements (REE) in soil around Kaduna Refinery. The aim of the study is to assess the rare elements potential of Nigeria for economic exploitation. Five REEs (La, Dy, Eu, Yb, and Lu) were detected in varying concentrations ranging from a minimum of 0.6 µg/g (Lu) to a maximum of 249.0 µg/g (La). The elements existed with trends consistent with the natural pattern of REEs in soil, showing significant Eu and Dy anomalies which characterize upper plains and flood plains. The levels of REEs in soil in the study area were generally slightly above background levels, with minimal (La, Dy, and Eu), moderate (Yb), and significant (Lu) enrichments and trending: Lu ˃Yb ˃ Eu ˃ Dy ˃ La. The abundance of the REEs investigated cannot establish a potential of Nigeria for economic exploitation of the mineral, hence, rare earth project in the study area is not viable at the moment.

References

Aubert, D., Probst, A. & Sille, P. (2004). Distribution and Origin of Major and Trace Elements (particularly REE, U and Th) into Labile and Residual Phases in an Acid Soil Profile (Vosges Mountains, France). Applied Geochemistry, 19, 899 – 916.

Charalampides, G., Vatalis, K. I., Apostoplos , B., & Ploutarch – Nikolas, B. (2015). Rare Earth Elements: Industrial Applications and Economic Dependency of Europe. Procedia Economics and Finance 24, International Conference on Applied Economics (ICOAE), 126 – 135.

Chen, Z. (2011). Global Rare Earth Resources and Scenarios of future Rare Earth Industry. Journal of Rare Earths, 29(1), 1 – 6.

Ding, S. M., Liang, T., Zhang, C. S., Wang, L. J., & Sun, Q. (2006). Accumulation and Fractionation of Rare Earth Elements in a Soil-Wheat System. Pedosphere, 16, 82 – 90.

Glascock, M. D. (2005). Overview of Neutron Activation Analysis. University of Missouri Research Reactor Center, Columbia, MO.

Guimarães, G. M., Franklin, R. L., Figueiredo, A. G. M., Silva, P. S. C. & Fávaro, D. I. T. (2011). Enrichment Factor and Geoaccumulation Index Applied to Sediment Samples from Guarapiranga Reservoir, Brazil, for Metal and Trace Element Assessment. International Nuclear Atlantic Conference – INAC, Belo Horizonte, MG, Brazil, October 20 – 28, 2011

Han, G. & Liu, C. (2006). Dissolved Rare Earth Elements in River Waters Draining Karts Terrains in Guizhou Province, China. Aquatic Geochemistry, 13(1), 95 – 107.

Hanson, G. N. (1980). Rare Earth Elements in Petrogenetic Studies of Igneous Systems. Earth Planet Science Letters, 8, 371 – 406.

Henderson, P. (1984) In Henderson, P. (ed.). General Geochemical Properties and Abundances of the Rare Earth Elements: Rare Earth Elements Geochemistry, Volume 2, 1st Edition, Elsevier Science Publishing Company Inc., New York, 1 – 50.

Hong, F. H., Wei, Z. G., & Zhao, G. W. (2000). Effect of Lanthanum on aged Seed Germination of Rice. Biological Trace Elements Research, 75, 205 – 213.

Hu, Z., Haneklaus, S., Sparovek, G., & Schnug, E. (2006). Rare Earth Elements in Soils. Communication in Soil Science and Plant Analysis, 37(9-10), 1381 – 1420.

Khan, A. J., Akhter, G., Gabriel, H. F., & Shahid, M. (2020). Anthropogenic Effects of Coal Mining on Ecological Resources of the Central Indus Basin, Pakistan. International Journal of Environmental Research and Public Health, 17: 1255, doi: 10.3390/ijerph17041255

Loska, K. Wiechula, D. & Korns, I. (2004). Metal concentrations of farming soils affected by industry. Environment International, 30: 159 - 165

Laveuf, C. & Cornu, S. (2009). A Review on the Potentiality of Rare Earth Elements to Trace Pedogenetic Processes. Geoderma, 154, 1 – 12.

Onoja, M. A., Ewa, I. O. B., Oladipo, M. O. A., & Kassimu, A. A. (2018). Rare Earth Elements Patterns in soil around Kaduna Refinery, Kaduna State, Nigeria. Journal of Science, Technology and Mathematics Education (JOSTMED), 14(1): 13 – 19.

Rudnick, R. L. & Gao, S. (2003). Composition of the Continental Crust (in) Rudnick, R. L., Holland, H. D., and Turekian, K. K. (eds). Treatise on Geochemistry. Elsevier Pergamon, Oxford, UK, Volume 3: 1 - 7

Å muc, N. R., Donelec, T., Serafimovski, T., Donelec, M., & Vrhovnik, P. (2012). Geochemical Characteristics of Rare Earth Elements (REEs) in the paddy Soil and Rice (Oryza sativa L) System of KoÄani field, Republic of Macedonia. Geoderma, 183-184, 1 – 11.

Tang, W., Shan, B., Zhang, H., & Mao, Z. (2010). Heavy metal sources and associated risk in response to agricultural intensification in the estuarine sediments of Chaohu lake valley, East China. Journal of Hazardous Materials, 176: 945 - 951

Tyler, G. (2004). Rare Earth Elements in Soil and Plant Systems – A Review. Plant and Soil, 267(1 – 2), 191 – 206.

Wang, L. & Liang, T. (2015). Geochemical Fractions of Rare Earth Elements in Soil around a Mine Tailing in Baotou, China. Scientific Reports, 5: 12483, doi: 10.1083/srep12483

Wedepohl, K. H. (1995).The composition of the continental crust. Geochimica et Cosmochimica Acta, 59: 1217 - 1232

Willis, S. S. & Johannesson, K. H. (2011). Controls on the Geochemistry of Rare Earth Elements in Sediments and Ground Waters of the Aquia Aquifer, Maryland, USA. Chemical Geology, 285, 32 – 49.

Zhang, J. & Liu, C. L. (2002). Riverine Composition and Estuarine Geochemistry of Particulate Metals in China – Weathering Features, anthropogenic impact and chemical fluxes. Estuarine Coastal Shelf Science, 54:1051 - 1070

Zhou, B., Li, Z., & Chen, C. (2017). Global Potential of Rare Earth Resources and Rare Earth Demand from Clean Technology. Minerals, 7(203); doi:10.3390/min7110203

Published
2020-07-12
How to Cite
OnojaM. A., BukarP. H., OmejeC. U., & AdamuA. M. (2020). ESTIMATION OF THE ABUNDANCE AND DISTRIBUTION OF RARE EARTH ELEMENTS IN SOIL AROUND KADUNA REFINING AND PETROCHEMICAL COMPANY USING NUCLEAR TECHNIQUE. FUDMA JOURNAL OF SCIENCES, 4(2), 599 - 604. https://doi.org/10.33003/fjs-2020-0402-243