QUANTITATIVE DETERMINATION OF PHYTOCHEMICAL CONSTITUENTS OF FRACTIONS OBTAINED FROM Ficus asperifolia LEAVES MIQ (MORACEAE) AND THE CHARACTERIZATION OF COMPOUNDS IDENTIFIED IN THE RESIDUAL AQUEOUS FRACTION

Authors

  • Ibrahim Doma Abdullahi
    Department of Pharmacology Bayero Univesity Kano
  • Hauwa Yahaya Umar
    Federal college of Education (T) Gombe
  • Umar Bello Suleiman
    Faculty of Sciences, Bayero University, Kano.
  • Abdullahi Rabiu Abubakar
    Faculty of Pharmaceutical Sciences, Bayero University, Kano
  • Adamu Yusuf Maitama
    Faculty of Pharmaceutical Sciences, Bayero University, Kano
  • Abdullahi Rahana Ameera
    Faculty of Pharmaceutical Sciences, Bayero University, Kano
  • Abdullahi Hamza Yaro
    Faculty of Pharmaceutical Sciences, Bayero University, Kano

Keywords:

Fractionation, Phytochemical, Quantitative, Metabolites, Ficus asperifolia

Abstract

Ficus asperifolia (Miq), family Moraceae is popularly known as sand-paper tree that is found in marshy areas around river banks. In Nigeria, it is called kawusa by Hausa tribe, ipin by Yoruba tribe and asesa or amerenwa by Igbo tribe. This research aims to quantify secondary metabolites present in the crude methanol extract and fractions and to characterize the identified compounds in the residual aqueous fraction of Ficus asperifolia leaves. The powdered fruit was extracted using 6L of 70% methanol. The crude extract was dissolved in water and fractionated using chloroform, ethylacetate, and n-buthanol. Phytochemical screening was conducted to determine the chemical composition of crude methanol leaf extract of Ficus asperifolia and its fractions. The phytochemical screening conducted revealed the presence of saponins, tannins, flavonoids, alkaloids, steroids and cardiac glycosides. Quantitative analysis of total alkaloids, flavoniods, saponins, and cardiac glycosides was also carried out. The crude extract fractionated produced 16.5% of chloroform, 6.8% of ethylacetate, 5.9% of n-butanol and 70.8% of residual aqueous fractions. The extract was further characterized using the available spectroscopic techniques such as FT-IR, UV, and GC-MS respectively.

Author Biographies

Hauwa Yahaya Umar

Department of Chemistry. Federal college of Education (T) Gombe

Umar Bello Suleiman

Department of Pure and Applied Chemistry, Faculty of Sciences, Bayero University, Kano.

Abdullahi Rabiu Abubakar

 

Department of Pharmacology and Therapeutics, Bayero University, Kano, Nigeria

 

Adamu Yusuf Maitama

 

Department of Pharmacology and Therapeutics, Bayero University, Kano, Nigeria

 

Abdullahi Rahana Ameera

Department of Pharmacology Bayero University, Kano

Abdullahi Hamza Yaro

 

Department of Pharmacology and Therapeutics, Bayero University, Kano, Nigeria

Dimensions

Anish M., Fabian B., Jesper G. A., Fredrik H., (2016). “A review of solar Energy Based heat and power generation Systems”, Renewable and Sustainable Energy Reviews, vol. 67, pp. 1047–1064.

Balema V., (2009). “Alternative Energy Photovoltaics, Ionic Liquids, and MOFs,” Material Matters, vol. 4, no. 4, p. 1.

Du H. J., Wang W. C., and Zhu J. Z., (2016). “Device simulation of lead-free CH3NH3SnI3 perovskite solar cells with high efficiency,” Chinese Physics B, vol. 25.

Aditi T., Akshay J., Vipul K., Opanasyuk A. S., and Panchal C. J., (2017). “Numerical Simulation of Tin Based Perovskite Solar Cell: Effects of Absorber Parameters and Hole Transport Materials”, Journal of Nano and Electronic Physics. Vol. 9 No 3, 03038(4pp) DOI: 10.21272/jnep.9(3).03038

Hossain M. I., Nouar T., and Fahhad H. A., (2015). "Copper oxide as inorganic hole transport material for lead halide perovskite based solar cells." Solar Energy 120: 370-380.

Salah M. M., Kamel M. H., Mohamed A., and Ahmed S., (2018) “A Comparative Study of Different ETMs in Perovskite Solar Cell with Inorganic Copper Iodide as HTM”, Optik, https://doi.org/10.1016/j.ijleo.10.052

Usha M., Victor V. S., Thyagarajan K., Raja R. M., and Babu B. J., (2017). “Design andsimulation of high efficiency tin halide perovskite solar cell”, International journal of renewable energy research Vol.7, No.4

Huang L., Sun X., and Li C., (2016). “Electron transport layer-free planar perovskite solar cells: further performance enhancement perspective from device simulation”, Solar Energy Materials and Solar Cells, vol. 157, pp. 1038–1047.

Minemoto T., and Murata M., (2014). “Impact of work function of back contact of perovskite solar cells without hole transport material analyzed by device simulation,” Current Applied Physics, vol. 14, pp. 1428–1433.

Bube R.H., (1998). Photovoltaic Materials. London: Imperial College Press.

Burgelman M., Nollet P., and Degrave .S., (2000). Thin Solid Films 361, 527.

Mohammed Y. O., Joshua A. O., Jessica A. U., Alex B. B., and Ugbe R. U., (2020). “The study and characterization of lead-free tin perovskite solar cell with high efficiency using SCAPS”, Journal of NAMP. Vol 55. P139-153

Gu Y.F., Du H.J., Li N.N., Yang L., and Zhou C.Y., (2019). “Effect of carrier mobility on performance of perovskite solar cells”. Chinese physicist B, 28(4): 048802

Behrouznejad F., Shahbazi S., Taghavinia N., Diau H.P. Wu, and E. W.G., (2016). “A study on utilizing different metals as the back contact of CH3NH3PbI3 perovskite solar cells”, Journal of Materials Chemistry A, vol. 4, pp. 13488–13498.

Haider S. Z., Anwar H. and Wang M., (2018). “A comprehensive device modelling of perovskite solar cell with inorganic copper iodide as hole transport material”, Semiconductor Science and Technology 33035001. 12pp.

Burschka .J. Pellet N., Moon S.J., Humphry-Baker R., Gao P., Nazeeruddin M.K., and Gratzel M., (2013). Sequential deposition as a route to high-performance Perovskite sensitized solar cells. Nature 499, 316–319.

Casas, G. A., Cappelletti, M. A., Cédola, A. P., Soucase, B. M., and Blancá, E. P. (2017). Analysis of the power conversion efficiency of perovskite solar cells with different Material as Hole-Transport Layer by numerical simulations. Super lattices and Microstructures, 107, 136-143.

Kojima, A., Teshima, K., Shirai, Y., and Miyasaka, T. (2009). Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. Journal of the American Chemical Society, 131(17), 6050-6051.

Lee, M. M., Teuscher, J., Miyasaka, T., Murakami, T. N., and Snaith, H. J. (2012). Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science, 1228604.

Liu, F., Zhu, J., Wei, J., (2014). “Numerical simulation: toward the design of high Efficiency planar perovskite solar cells,” Applied Physics Letters, vol. 104, article 253508.

Liu P., Singh V. P., Jarro C. A., and Rajaputra S., (2011). “Cadmium sulfide nanowires for the window semiconductor layer in thin film CdS – CdTe solar cells,” Nanotechnology, vol. 22, no. 14.

Chen Q.Y., Huang Y., Huang P.R., Ma T., Cao C., and He Y. (2016). “Electro negativity Explanation on the efficiency-enhancing mechanism of the hybrid inorganic-organic perovskite ABX3 from first principles study” China Physics B, DOI:10.1088/1674- 1056/25/2/027104, Vol. 25, No. 2pp.027104-1-6.

Fahrenbruch A.L., and Bube R.H., (1983). Fundamentals in Solar Cells. New York: Academic Press.

Stamate M. D., (2003). "On the dielectric properties of dc magnetron TiO2 thin films", Applied Surface Science 218, no. 1-4: 318-323.

Rahman I., Sakib F., Sarwar A., and Tanvir I. D., (2017). "A comparative study on different HTMs in perovskite solar cell with ZnOS electron transport layer." In Humanitarian Technology Conference (R10-HTC), IEEE Region 10, pp. 546-550. IEEE.

Christians J. A., Raymond C. F., and Prashant V. K., (2013) "An inorganic hole conductor for organo-lead halide perovskite solar cells. Improved hole conductivity with copper iodide", Journal of the American Chemical Society 136, no. 2. 758-764.

Sepalage G. A., Steffen M., Alexander P., Andrew D., Scully F. H., Udo B., Leone S., and Yi B. C., (2015). "Copper (I) iodide as hole-conductor in planar perovskite solar cells: probing the origin of J–V hysteresis." Advanced Functional Materials 25, no. 35: 5650- 5661.

Frolova L. A., Dremova N. N., and Troshin P. A., (2015). “The chemical origin of the p-type and n-type doping effects in the hybrid methylammonium–lead iodide (MAPbI3) Perovskite solar cells.” Chemical Communication 51. 14917–14920.

Fahrenbruch, A. L., and Bube, R. H,. (1983). Fundamentals of Solar Cells: Photovoltaic SolarEnergy Conversion. St Louis: Academic Press, 231-4

Published

17-11-2023

How to Cite

QUANTITATIVE DETERMINATION OF PHYTOCHEMICAL CONSTITUENTS OF FRACTIONS OBTAINED FROM Ficus asperifolia LEAVES MIQ (MORACEAE) AND THE CHARACTERIZATION OF COMPOUNDS IDENTIFIED IN THE RESIDUAL AQUEOUS FRACTION. (2023). FUDMA JOURNAL OF SCIENCES, 7(2), 330-343. https://doi.org/10.33003/fjs-2023-0702-2019

How to Cite

QUANTITATIVE DETERMINATION OF PHYTOCHEMICAL CONSTITUENTS OF FRACTIONS OBTAINED FROM Ficus asperifolia LEAVES MIQ (MORACEAE) AND THE CHARACTERIZATION OF COMPOUNDS IDENTIFIED IN THE RESIDUAL AQUEOUS FRACTION. (2023). FUDMA JOURNAL OF SCIENCES, 7(2), 330-343. https://doi.org/10.33003/fjs-2023-0702-2019