RECYCLING AND CHARACTERIZATION OF SPENT ENGINE OIL USING TWO STAGES: SOLVENT EXTRACTION AND CLAY PERCOLATION TECHNIQUES

  • Alexander Asanja Jock Department of Chemical and Petroleum Engineering, University of Uyo
  • Asabe Mercy Magomya
  • Saviour Etim Essang
Keywords: Clay, pollution, properties, solvent extraction, spent engine oil

Abstract

Spent lube oils are continuously generated from factories, vehicles and other machineries.  Most spent engine oil contains harmful substances such as heavy metals and indiscriminate disposal of this oil causes environmental pollution. The recycling of spent engine oil has also become important due to its economic benefits. In this study, solvent extraction and clay percolation techniques were used to recycle spent engine oil. The specific gravity, flash point, viscosity, pour point and total acid number. The specific gravity was 0.8252-0.8937, viscosity at 40oC was from 79.37 to 130.12cSt while at 100oC was 8.50 to 15.64 cSt.  The flash and pour points were 121-214 oC and -14 to -9oC respectively. The total acid number were 5.21 and 2.21 mgKOH/g for untreated oil, 0.43 and 0.315 mgKOH/g for treated oil while the total based number were 8.42 and 6.30 mgKOH/g for the treated oil.  The results suggested that this method can be employed to improve the quality spent engine oil for industrial applications as well as reducing environmental pollution due tospent engine oil.

References

Abdullahi, S. and Musa, M.S. (2023). Health Risk Assessment of Some Heavy Metals in Soil Samples Around Identified Metal Workshops.FUDMA Journal of Sciences (FJS). 7(2): 240-245. https://doi.org/10.33003/fjs DOI: https://doi.org/10.33003/fjs-2023-0702-1745

Adewole,B.z., Olojede, J.O., Owolabi, H.A. and Obisesan, O.R. (2019). Characterization and Suitability of Reclaimed Automotive Lubricating Oils Reprocessed by Solvent Extraction Technology.Recycling, 4(31): 1-11) doi:10.3390/recycling4030031 DOI: https://doi.org/10.3390/recycling4030031

Ahamad, T.M., ChadraSekhar, B.P., Mohan, P.N., Joshi, K.S. and Sree, T.D.R. (2015). Recycling and Analysis of Spent Engine Oil. International Journal of Scientific & Engineering Research, 6(11): 711-718.

ASTM D97-20 (2020). Standard Test Method for Pour Point of Petroleum Products. ASTM International, West Conshohocken, PA.

ASTM D-974 Designation Standard Test Method for Acid and Base Number of Petroleum Products by Color-28.

ASTM D-2896 (1995). Standard Test Method For Base Number Of Petroleum Products By Potentiometric Perchloric Acid Titration; Annual Book of ASTM Standards, West Conshohocken, PA, USA; Volume 5.01.

Boadu, O.K., Joel, O.F., Essumang, K.D. Evbuomwan, O.B. (2019). A Review of Methods for Removal of Contaminants in Used Lubricating Oil. Chemical Science International Journal, 1-11 DOI: https://doi.org/10.9734/CSJI/2019/v26i430101

Dinesh, K., Kaithari, K.D., Krishnan, K.P and Al-Rivami, A. (2021). Recycling of Used Lubricating Engine Oil by A Solvent Extraction Process. International Journal of mechanical and production engineering research, 11(1): 151-158 DOI: https://doi.org/10.24247/ijmperdfeb202114

Hsieh, H.C., Wang, C.-T., and Kuo, C.H. (2015). The effects of temperature and shear rate on the viscosity of engine oils. Tribology International: pp. 17-23.

Hamawand, I., Yusaf, T. and Rafat, S. (2013). Recycling of Waste Engine Oils Using a New Washing Agent. Energies, 6, 1023-1049. https://doi.org/10.3390/en6021023 DOI: https://doi.org/10.3390/en6021023

Kannan, C., Kumar, K.S., Hussain, M., Priya, N.and Saravanan, K. (2014). Studies of reuse of re-refined used automotive lubricating oil. Res. J. Eng. Sci. 3, pp. 8–14.

Kaurl, H., Singh, D. and Singh, N. (2019). Effect of clay percolation on the properties of used engine oil. Journal of Petroleum Science and Engineering, 181, 106188. DOI: https://doi.org/10.1016/j.petrol.2019.106188

Machado, F. A. L., Rodrigues, C. V., Luz, A. B., Medeiros, A. S. S., and Sousa, V. A. (2017). Recycling of used engine oil by different solvent extraction processes. Journal of Cleaner Production, 149, pp. 310-316.

Musa, A., Ahmed., M. J., and Isah, A. M., (2021). Improvement of specific gravity and flash point of used engine oil using local clay material. Results in Physics. 26, 104812.

Ogbeide, S. E., Osunde, Z. D., and Amanabo, M. U. (2020). Effect of acid and solvent extraction on the physicochemical properties of used engine oil. Nigerian Journal of Chemical Research, 25(1), pp. 67-79.

Ogbeide, S. O. (2010). An investigation to the recycling of spent engine oil.Journal of Engineering Science and Technology Review 3, pp. 32–35. DOI: https://doi.org/10.25103/jestr.031.06

SAE International, SAE J300: Engine oil viscosity classification. SAE International, Warrendale, PA, 2019.

Tawfik, A., Abouelkhair, B., Al-Zahrani, S., Al-Sulaiman, F., and Alabdullatif, J. (2021). Enhancement of the performance of used engine oil via solvent extraction and adsorption using kaolin clay. Journal of Applied Sciences, 11(1), 317.

Udonne, J.D., Efeovbokhan, V.E., Ayoola, A.A., Babatunde, D.E., Ifeoluwa, A. and Ajalo, l.J. (2016). Recycling used lubricating oil using untreated, activated and calcined clay methods. Journal of Engineering and Applied Sciences 11 (6): 1396-1401.

Ugwele, F.O., Aninwede, C.S., Chime, T.O., Christian, O.A. and Innocent, S.I. (2020). Application of response surface methodology in optimizing the process conditions for the regeneration of used mobil oil using different kinds of acids. Heliyon 6: 1-14. https://doi.org/10.1016/j.heliyon.2020.e05062 DOI: https://doi.org/10.1016/j.heliyon.2020.e05062

Yusuf, K. O., Adebayo, G. A., and Ayodele, O. S. (2021). Improvement of flash point of used engine oil using solvent extraction and activated clay adsorption methods. Journal of Petroleum Science and Engineering, 198, 108023.

Published
2023-06-30
How to Cite
Jock A. A., Magomya A. M., & Essang S. E. (2023). RECYCLING AND CHARACTERIZATION OF SPENT ENGINE OIL USING TWO STAGES: SOLVENT EXTRACTION AND CLAY PERCOLATION TECHNIQUES. FUDMA JOURNAL OF SCIENCES, 7(3), 182 - 185. https://doi.org/10.33003/fjs-2023-0703-1836