DEVELOPMENT OF ADSORBENTS FROM RICE HUSK FOR CESIUM REMOVAL FROM SIMULATED WASTE WATER USING CENTRAL COMPOSITE DESIGN

  • M. S. Olakunle
  • A. O. Ajayi
  • M. M. Alfa
  • A. A. Ahmadu
Keywords: Central composite design, Impregnation, Cesium, adsorption, adsorbent, Concentration.

Abstract

This paper deals with the production of adsorbents and adsorption studies for the uptake of Cesium (Cs) ions from aqueous solutions using carbonized rice husk composite as adsorbent. The carbonized rice husk and surface properties of the adsorbent were characterized by Scanning Electron Microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Brauner Emmet and Teller (BET) analyzer. Central Composite Design (CCD) was used to optimize the process variables such as initial metal ion concentration, Contact time, adsorbent dosage and pH of the solution on the performance of percentage removal and adsorption capacity. The experimental data were validated with different isotherms and kinetic models to assess the solute interaction behavior and nature of adsorption. The maximum adsorption capacity for (a) rice husk (8.03mg/g) and impregnated rice husk (b) (13.58 mg/g) adsorbents were fully evaluated. Revealing the reliability and suitability of the optimization approach .In addition, the results of isotherm study show that the Langmuir model can be used to best describe the adsorption behavior of Cs on to the rice husk and impregnated rice husk composite s adsorbents

References

Al-Muhtaseb SA, Ritter JA (2003) “Preparation and Properties of Resorcinol–Formaldehyde Organic and Carbon Gels”. Adv.Mater, 15:101-114.

Amit Bhatnagar, Minoch a.k. (2006.) “Conventional and non-Conventional Adsorbents for Removal of Pollutants from Water – A Review”. Indian Journal of Chemical Technology, 13, 203,

Esfandiar .N, B. Nasernejad , T. Ebadi (2014), “Removal of Mn(II) from groundwater bysugarcane bagasse and activated carbon (a comparative study)” application of response surface methodology (RSM), J. Ind. Eng. Chem. 20,3726–3736

F. Ghorbani , H. Younesi , G. Seyed , Z. Ali , M. Amini , D. Ali ,(2008) “Application of response surface methodology for optimization of cadmium biosorption in an aqueous solution by Saccharomycescerevisiae”. Chemical Engineering Journal, 145,267–275 .

Gupta V.K. and Ali I.(2013), “Environmental Water Advances in Treatment, Remediation and Recycling” http://dx.doi. org/10.1016/B978-0-444-59399-3.00001-5,

Gonzales m.t., Rodriguez-reinoso F., Garcia A.N., Marcilla A. (1997) “CO2 Activation of Carbonized under Different Experimental Conditions Carbon” 35, 159,

K. Kadirvelu , K. Thamaraiselvi , C. Namasivayam , (2001) “Removal of heavy metals from industrial wastewaters by adsorption onto activated carbon prepared from an agricultural solid waste”. Bioresour .Technol. 76 63–65 . K. Kadirvelu ,

K. Kadirvelu , C. Faur-Brasquet , P. Cloirec , (2000) “Removal of Cu (II), Pb (II), and Ni (II) by adsorption onto activated carbon cloths”. Langmuir 16 8404–8409

Merzougui Z., Addoun F. (2008). “Effect of Oxidant Treatment of Date Pit Activated Carbons Application to the Treatment of Waters”. Desalination,394,

Mohamed E.F. , (2011). ‘Removal of organic compounds from water by adsorption and photo-catalytic oxidation”.Thesis is Submitted for the Degree of Doctoral”. Institute National Polytechnique Toulouse: http://ethesis.inp-toulouse.fr/ archive/00001569/01/mohamed.pdf, 2011.

Monser L., Adhoum N.(2011). “Modified Activated Carbon for the Removal of Cu(II), (II),Cr, and Cyanide from Wastewater” . Separation and Purification Technology,2011

Mohamed Sulyman (2016).Chemical faculty, Gdansk University of Technology, Poland. Pol. J. Environ. Stud. Vol. 26, No. 2 (2017), 479-510

NomanbhayS.M., Palanisamy K.,(2005) “Removal of Heavy Metals from Industrial Wastewater Using Chitosan Coated Oil Palm Shell Charcoal”.Electron J. Biotecnol, 2005, http://www.ejbiotnology.info/content/vol8/ issue.full.7.bip/index.htm

Sulyman M.,(2014). “Fixed-bed Column Packed with Low-cost Spent Tea Leaves for the Removal of Crystal Violet from Aqueous Solution”.5th International Conference on Science and Technology, Gdansk-Poland,

Satish P., Vaijanta D., Sameer R., and Naseems P. (2011) .Kinetics of Adsorption of Crystal Violet from Aqueous Solution Using Different Natural Materials. International Journal of Environmental Sciences, ISSN 0976-4402,

Sugashini. S. K.MMeeraSheriffa Begum (2012) Optimization of Central composite Design (CCD) for the removal of Cr (VI) ions by cross linked chitosan carbonized rice husk (CCACR) Clean Tech Environ Policy(2013) 15:293-302

Shuqiong Li , Hang Wang , Liang Yan , GanTian and Shoujian Li. (2009). Supporting of Potassium Copper Hexacyanoferrate on Porous Activated Carbon Substrate for Cesium Separation”. Separation Science and Technology, 44: 4023–4035, (2009) Taylor & Francis Group, LLC. College of Chemistry, Sichuan University, Chengdu, P. R. China

Shekhar L. Pandharipande, Grishma A. Borkar.(2016). Synthesis, Characterization and Adsorption Study of Composite Adsorbent using Corncob and Cornstarch International Journal of Science, Engineering and Technology Research (IJSETR), 5(5)

Srivastava, V.C., I.D. Mall and I.M. Mishra, 2006. Characterization of mesoporous rice husk ash (RHA) and adsorption kinetics of metal ions from aqueous solution onto RHA. Journal of Hazardous Material”., 134: 257-267.

T.M. Alslaibi, I. Abustan ,Mohd A . Ahmad , A .A (2013) Foul , Cadmium removal from aqueous solution using microwaved olive stone activated Carbon,. Journal Environmental Chemical Engineering

W. T. Tsai, C. Y. Chang, S. Y. Wang, C. F. Chang, S. F. Chien, and H. F. Sun1 (2001). agricultural Waste corn cob for the preparation of carbon adsorbent.Journal of Environmental Science and Health, b 36(5), 677–686 .2001

Youli Zong, Yongde Zhang, Xiaoyan Lin, Dong ye, Dan Qiao and Shuangneng (2017). Facile synthesis of potassium copper Ferro cyanide composite particles for selective cesium removal from waste water in the batch and continuous process. Department of material science and engineering,Mianyang.

Y. Huang , S. Li , J. Chen , (2014) X. Zhang , Y. Chena Adsorption of Pb(II) on mesoporous activated carbons fabricated from water hyacinth using H3PO4 activation: Ad-sorption capacity, kinetic and isotherm studies” Applied Surface Science, 293: 160–16

Y. Han , L. Weiwei , J. Zhang , H. Meng , Y. Xua , X. Zhang , (2015). Adsorption behavior of Rhoda mine B on nanoporouspolymers RSC Adv. 5 104915–104922

Y. Huang , S. Li , H. Lin , J. Chen , (2014) .” Fabrication and characterization of mesoporous activated carbon from Lemna minor using one-step H3PO4 activation for Pb(II) removal, .Applied Surface Science, 317 422–431

Published
2023-04-11
How to Cite
OlakunleM. S., AjayiA. O., AlfaM. M., & AhmaduA. A. (2023). DEVELOPMENT OF ADSORBENTS FROM RICE HUSK FOR CESIUM REMOVAL FROM SIMULATED WASTE WATER USING CENTRAL COMPOSITE DESIGN. FUDMA JOURNAL OF SCIENCES, 3(3), 462 - 471. Retrieved from https://fjs.fudutsinma.edu.ng/index.php/fjs/article/view/1592

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