PREPARATION OF COMPATIBLE AND BIODEGRADABLE ACETYLATED CASSAVA STARCH/POLY (STYRENE-alt-MALEIC ANHYDRIDE) BLENDS USING POLYETHYLENE GLYCOL (400) AS PLASTICIZER
Abstract
The study was carried out to investigate the compatibility and biodegradability profile of acetylated cassava starch/poly(styrene-alt-maleic anhydride) blends using Polyethylene glycol (400) as plasticizer. Native cassava starch (NCS) was successfully acetylated at room temperature using acetic anhydride and 1M NaOH. The percentage acetylation and degree of substitution were found to be 5.38 % and 0.21 % respectively. Polymer blend films of Acetylated cassava starch (ACS) and poly (styrene-alt-maleic anhydride) (PSAMA) were prepared by casting technique. Biodegradation profile of the polymer film was evaluated by soil burial method and % water absorption of polymer blend were also determined as 1.31 % and 9.38 % respectively. Native cassava starch (NCS), acetylated starch (ACS) and their corresponding blends were further characterized by FTIR (CARY 630 AGILENT). The results obtained indicated an interaction between the two polymers. Scanning electron micrographs (SEM) of the polymer blend indicated a very good compatibility
References
Chiellini E, Corti A., Swift G. (2003) biodegradation of thermally oxidized fragmented LDPE. Polymer Degradation and Stability, 81; 341-351
Raj B., Sankar U. (2004) LDPE/starch blend films for packaging application. Advance Polymer Technology. 23(1): 33-45.
Lloyd (2014) Historical Perspective of Advances in the Science and Technology of Polymer Blends. Polymers. 6: 1251-1265
Chen, L., X. Qiu, Z. Xie, Z. Hong, J. Sun, X. Chen, and X. Jing. Poly(L-lactide)/starch blends compatibilized with poly(L-lactide)-g-starch copolymer. 2005. Carbohydrate Polymers 65: 75-80.
BeMiller JN, Whistler RL. (1984) Starch Chemistry and Technology. 2nd ed. London, UK Academic Press Publications; 879.
Ramkumar, D. H. S., Bhattacharya, M. (1997). Effect of crystallinity on the mechanical properties of starch/synthetic polymer blends. Journal of Material Science: 32 2545-2572.
Paul, D. R. and Bucknall C. B. (2000) polymer blends formulation. John Wiley and Son Inc. N.Y 1; pg600.
Phillips DL, Huijum L, Duohai P, Harold C. (1999) general application of Raman spectroscopy for the determination of level of acetylation in modified starches. Cereal Chem 76(3); 439-443
Elomaa M, Asplund T, Sointein P, Laatikainem R, Peltonen S, Hyvainen S. and Urtti A. (2004) determination of the degree of substitution of acetylated starch by hydrolysis, H NMR and TGA/IR. Carbohydrate Polymers: 57; 261-267.
Fahmida Parvin, Md. Arifur Rahman, Jahid M. M. Islam, Dr. Mubarak A. Khan and A. H. M. Saadat (2010) preparation and characterization of starch/PVA blend for biodegradable packaging material. Advanced Materials Research vol. 123-125; 351-354
Singh, N., Chawla D, Singh J (2004). Influence of acetic anhydride on physicochemical, morphology and thermal properties of corn and potato starch. Food Chemistry: 86 (4) 601-608.
Emeje M., Kalita R, Isimi C, Buragohain A, Kunle O and S. Ofoefula (2012) synthesis and characterization and physicochemical characterization and functional properties of esterified starch from an underutilized source in Nigeria. African Journal of Food, Agriculture, Nutrition and Development 12 (7):7001-7018
Kaur L., N. Singh, J. Singh, N. S. Sodhi, and B. S. Gill, (2003) “Review: Morphological, thermal and rheological properties of starches from different botanical sources,” Food Chemistry, vol. 81, pp. 219-231.
Francisco, P. G., Judith, P. M., Maria, A. M. M., Lius, A. B. P., and Alma, D. R. G. (2012) modification and chemical characterization of barley starch. International Journal Applied Science and Technology. 2 (4) 30-39.
Prachayawarako J., Sangnitidej P., Boonpasith, P. (2010) properties of thermoplastic rice starch composite reinforced by cotton fiber or LDPE. Carbohydrate Polymers 81 425-433
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