ANALYSIS AND CHARACTERIZATION OF BIODIESEL PRODUCTION FROM Glycine max SEED OIL USING ALKALI CATALYST

  • M. M. Lawan
  • S. Serder
Keywords: Glycine max, biodiesel, transesterification, alkali, catalyst.

Abstract

Due to the increasing energy demand and the pollution problems caused by the use of fossil fuels, the used of vegetable oils and their derivatives as alternative for diesel fuel is the best solution in the current scenario. Nowadays the use of biodiesel as a substitute for conventional diesel engine has been of great interest. This study aim to evaluate the analysis and characterization of the biodiesel production from Glycine max based on the yield of the oil extracted from the seed. The percentage oil content of Glycine max seed is found to be  17.10 %.The result of this research also signifies the identification of the optimum characterization of the physical and chemical parameters from the extracted oil and biodiesel production by transesterification using alkali catalyst such as pH, moisture content, specific gravity, kinematic viscosity at 40°C, refractive index, acid value, saponification value, iodine value, flash point, Fatty acid methyl ester (FAME) and identification of functional groups. The fatty acid methyl ester analyzed using GCMS contains palmitic acid 15.4, oleic acid 28.9, linoleic acid 54.4, arachic 1.2. The FTIR results also conform that the, Glycine max having 1769 cm -1 is attributed to carbonyl (C=O) of typical esters which ranged 1800-1700 cm -1.All the results of the seed oil and the biodiesel were conformed to the standard specified by USA (ASTM D6751) and European organization (EN 14214) and they have met the specified standard recommendations for suitably used in conventional diesel engines.

References

Abayeh, O.J., Aina, E.A., and Okoonghae, C.O., (1998). Oil content and oil quality characteristics of some Nigerian oil seeds. Journal of Pure and Applied Science, 1(1), 17-23.

Akpan, U.G., Jimoh, A. and Mohammed, A.D. (2006), Extraction, Characterization and modification of Castor Seed Oil. Leonardo Journal of Sciences, 8: 43-52.

ASTM, (2002). ASTM D6751-08: Standard specification for biodiesel fuel (B100) blend stock for distillate fuels Annual Book of ASTM Standards (West Conshohocken, PA: ASTM International).

Azam, M.M, Waris. A., Nahar, N.M,( 2005). Prospect and potential of fatty acid methyl esters of some non- traditional seed oil for use as a biodiesel in India. Biomass and Bioenergy; 29:293-302.

Belewu M.A , F.K. Adekola , G.B. Adebayo , O.M. Ameen, N.O. Auhammed , A.M. Alaniyan ,O.F. Adekola and A.K. Musa, physico-chemical characteristics of oil and biodiesel from Nigerian and Indian Jatropha curcas seeds. International Journal of Biological Chemical Sciences 4(2): 524-529

Bockey, D., (2006). Biodiesel in Germany: Market Trends and Competition Union for Promoting Oil and Protein Plants.

Doan, L.G., (2004). Ricin: Mechanism of Toxicity, Clinical Manifestations and Vaccine Development. A Review of the Toxicology, 42: 201–208.

Domínguez L Á A 1996 Biofuels: Use of Vegetable Oils as Renewable Energy (Madrid: Ministry of Agriculture, Fisheries and Food)

Ene-Bong, H.N., Carnovale, E., (1992). Comparison of the proximate mineral and amino acid composition of some known and lesser known legume s in Nigeria. Food Chemistry. 43,169– 175.

Gunstone, F.D., (1994). The chemistry of oils anf fat: sources, composition, properties and uses.Blackwell publishing limited, London uk.

Izuagie, A., Akpambang, V.O.E., Amoo, A. (2008). Comparative compositional analysis on two varieties of melon (Colocynthis citrullus and Cucumeropsis edulis) and a variety of almond (Prunus amydalus). Journal of Agricultural and Biological Sciences, 4(6): 639-642.

Jain, S., and Sharma, M.P., (2010).Renewable Sustainable Energy Reviews. (14):667

Kyari M.Z. (2008), Extraction and Characterization of Seed Oils, International Agrophysics, 22:139-142.

Mielenz, J.R., Bardsley, J.S., Wyman, C.E. (2009).Fermentation of soybean hulls to ethanol while preserving protein value. Bioresource Technology, 100(14):3532-9.

Oderinde RA, Ajayi IA, Adewuyi A (2009). Characterization of seed and seeds oil of Hura Crepitans and the kinetics of degradation of the oil during heating. Electron. Journal of Environmental Agricultural and Food Chemistry, 8(3): 201- 208

Penugonda, S.B., and Venkata, R.M., (2012). Methanolysis of Castor Oil for Production of Biodiesel. International Journal of Advanced Engineering Technology, 3:146-148.

Pimentel,D., and Patzek, T.,(2005). Ethanol Production Using Corn, Switchgrass, and Wood; Biodiesel Production Using Soybean and Sunflower 14, (1) 65-76

Qi, D.H., Geng, L.M., Chen, H., Bian, Y.Z., Liu, J., Ren, X.C. (2009). Combustion and performance evaluation of a diesel engine fueled with biodiesel produced from soybean crude oil. Renewable Energy, 34(12), 2706-2713.

Salunke, D.K. and Desai, B. B.(1941), Post-harvest Biotechnology of Oil Seeds, CRC Press, .161-170.

Silva, G.F., Fernando, L.C., Andrea L.O.F. (2011). Application of response surface methodology for optimization of biodiesel production by transesterification of soybean oil with ethanol. Fuel Processing Technology; 92:407–413.

Soares, I. P.; Rezende, T. F.; Silva, R. C.; Castro, E. V. R.; Fortes, I. C. P.( 2008). Energy Fuels, 22, 2079.

Ullah, F., Bano A., and Ali, S., (2013).Optimization of protocal for biodiesel production of lin seed (Linum Usitatissiumum L.) oils. Polis Journal of Chemical Technology. 15: 74–77.

Published
2023-03-30
How to Cite
LawanM. M., & SerderS. (2023). ANALYSIS AND CHARACTERIZATION OF BIODIESEL PRODUCTION FROM Glycine max SEED OIL USING ALKALI CATALYST. FUDMA JOURNAL OF SCIENCES, 3(1), 84 - 90. Retrieved from https://fjs.fudutsinma.edu.ng/index.php/fjs/article/view/1430